4-(2,2,3,4,4,4-hexafluorobutoxy)-1,1,1,2,3,3-hexafluorobutane | 1224851-85-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(2,2,3,4,4,4-hexafluorobutoxy)-1,1,1,2,3,3-hexafluorobutane
• 英文别名: 1,1,1,2,3,3-Hexafluoro-4-(2,2,3,4,4,4-hexafluorobutoxy)butane
• CAS: 1224851-85-7
• 化学式: C₈H₆F₁₂O
• 分子量: 346.116
• InChiKey: NZTJEUOBZCMJEU-UHFFFAOYSA-N

物化性质

• 沸点：
  158.0±40.0 °C(Predicted)
• 密度：
  1.483±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  六氟丁醇 、 2,2,3,4,4,4-hexafluorobutyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate 在 三正丁胺 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 18.0h， 生成 4-(2,2,3,4,4,4-hexafluorobutoxy)-1,1,1,2,3,3-hexafluorobutane
  参考文献：
  名称：

  METHODS OF MAKING FLUORINATED ETHERS, FLUORINATED ETHERS, AND USES THEREOF

  摘要：

  一种制备氟化醚的方法包括在极性无水溶剂中结合以下物质：由公式X—Rf1CH2OH表示的氟化醇，以及由公式Rf2CH2OS(═O)2Rf3表示的氟化磺酸酯酯和碱；并获得由公式Y—Rf1CH2OCH2Rf2—Y表示的氟化醚。其中，Rf1选择自具有1至10个碳原子的全氟化C1-C10烷基基团和部分氟化C1-C10烷基基团，以及具有连续杂原子的衍生物。X代表H、F或HOCH2—基团。Rf2选择自全氟化C1-C10烷基基团和部分氟化C1-C10烷基基团，以及具有连续杂原子的衍生物。Rf3是C1-C4烷基基团。Y代表H、F或Rf2CH2OCH2—基团。还公开了一种用于制备对称氟化醚的变种方法。本公开还提供了根据该方法可制备的氟化醚。还公开了氟化醚在各种应用中的使用。

  公开号：

  US20100108934A1

文献信息

• NOVEL FLUORINE-CONTAINING ETHER COMPOUND
  申请人：ITO Takayuki

  公开号：US20090018350A1

  公开（公告）日：2009-01-15

  A fluorine-containing ether compound with a fluorine content increased, the fluorine content being enhanced by fluorinating a polymer including a repeating unit represented by the following Formula (I): wherein Rh 1 represents a divalent linkage group; Rf 2 represents an perfluoroalkylene group; each of Rf 3 and Rf 4 independently represents a fluorine atom, a perfluoroalkyl group or a perfluoroalkoxy group, and any two of Rf 2 , Rf 3 and Rf 4 may be combined with each other to form a ring.

  一种含氟醚化合物，其氟含量增加，氟含量通过对包括由以下式（I）表示的重复单元的聚合物进行氟化而增强：其中Rh1表示二价连接基团；Rf2表示全氟烷基烯基团；Rf3和Rf4中的每一个独立地表示氟原子、全氟烷基团或全氟烷氧基团，Rf2、Rf3和Rf4中的任意两个可以结合在一起形成环。
• METHODS OF USING HYDROFLUOROETHERS AS HEAT TRANSFER FLUIDS
  申请人：FLYNN Richard M.

  公开号：US20110100601A1

  公开（公告）日：2011-05-05

  An apparatus is provided that includes a device and a mechanism for heat transfer. The mechanism includes a hydrofluoroether heat-transfer fluid wherein the heat transfer fluid is represented by the following structure: Y—R f —CH 2 OCH 2 R f —Y wherein R f may be the same or different and is, independently, selected from the group consisting of perfluorinated alkylene groups which may be linear, cyclic, or branched having from 1 to 10 carbon atoms, partially fluorinated alkylene groups having from 1 to 10 carbon atoms, and derivatives thereof wherein one or more carbon atoms are replaced by catenated nitrogen or oxygen heteroatoms, wherein each R f contains at most one hydrogen atom, wherein Y represents H, F, or an R f CH 2 OCH 2 — group, and wherein the total number of carbon atoms in the molecule is at least 6. A method of transferring heat including the device and the provided heat-transfer fluid is also provided

  提供了一种装置，包括设备和用于传热的机制。该机制包括一种氢氟醚传热流体，其中所述传热流体由以下结构表示：Y—Rf—CH2OCH2Rf—Y，其中Rf可以相同或不同，独立地从以下组中选择：具有1至10个碳原子的全氟烷基，可以是线性、环状或支链的，具有1至10个碳原子的部分氟化烷基和其衍生物，其中一个或多个碳原子被串联的氮或氧杂原子所取代，其中每个Rf分子中最多含有一个氢原子，其中Y表示H、F或RfCH2OCH2-基团，分子中的总碳原子数至少为6。还提供了一种包括所述装置和提供的传热流体的传热方法。
• Thermal insulating foamed material and method of manufacturing the same
  申请人：MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

  公开号：EP0723989A2

  公开（公告）日：1996-07-31

  The present invention provides a thermal insulating foamed material with excellent thermal insulating properties and a method of manufacturing the same. The method comprises the steps of: concurrently mixing and blowing a polyurethane material to produce a foamed polyurethane resin composition with a multiplicity of closed cells, the polyurethane material including a reactive blowing agent, a volatile compound having a boiling point of not higher than 150°C and a molecular weight of not less than 70, an epoxy compound, and a carbon dioxide fixation catalyst, wherein the closed cells are filled with the volatile compound and carbon dioxide produced by a reaction of the reactive blowing agent with a polyisocyanate; and allowing the carbon dioxide to chemically react with epoxy groups of the epoxy compound in the presence of the carbon dioxide fixation catalyst to form a solid or liquid cyclic carbonate. The method gives a foamed material with the closed cells substantially filled with vapor of the volatile compound at a partial pressure of at least 5 mmHg at 25°C.

  本发明提供了一种具有优异隔热性能的隔热发泡材料及其制造方法。该方法包括以下步骤同时混合和发泡聚氨酯材料，以生产具有多个闭孔的发泡聚氨酯树脂组合物，该聚氨酯材料包括活性发泡剂、沸点不高于 150℃、分子量不小于 70 的挥发性化合物、环氧化合物和二氧化碳固定催化剂，其中闭孔由挥发性化合物和活性发泡剂与多异氰酸酯反应产生的二氧化碳填充；让二氧化碳在二氧化碳固定催化剂存在下与环氧化合物的环氧基团发生化学反应，形成固态或液态环状碳酸盐。该方法可得到一种发泡材料，在 25°C 分压至少为 5 mmHg 时，闭孔基本上充满了挥发性化合物的蒸汽。
• FLUORORESIN, FLUORORESIN PARTICLES, AND METHODS FOR PRODUCING THESE
  申请人：Tosoh Corporation

  公开号：EP3858873A1

  公开（公告）日：2021-08-04

  The present invention relates to resin particles including a residue unit represented by the following general formula (1) and having a volume average particle diameter equal to or more than 5 µm and equal to or less than 2000 µm, and a method for producing thereof. Fruthermore the present invention relates to a fluororesin comprising a residue unit represented by a general formula (1) and having a weight average molecular weight Mw in a range of 5 × 104 to 3 × 105, and a yellow index of a heat-melted molded product (thickness 3 mm) after 24 h at 280°C of equal to or less than 6, and a method for producing thereof. In the formula (1), Rf1, Rf2, Rf3, and Rf4 are each independently one of the groups consisting of a fluorine atom, a linear perfluoroalkyl group having 1 to 7 carbon atoms, a branched perfluoroalkyl group having 3 to 7 carbon atoms, or a cyclic perfluoroalkyl group having 3 to 7 carbon atoms. The perfluoroalkyl group may have an ethereal oxygen atom. Further, Rf1, Rf2, Rf3, and Rf4 may be linked to one another to form a ring having 4 or more and 8 or less carbon atoms, and the ring may include an ethereal oxygen atom.

  本发明涉及一种树脂颗粒，包括由以下通式(1)表示的残余物单元，其体积平均颗粒直径等于或大于5微米，等于或小于2000微米，以及生产这种树脂颗粒的方法。此外，本发明还涉及一种含通式（1）表示的残余物单元的氟树脂，其重量平均分子量 Mw 在 5×104 至 3×105 之间，在 280℃下 24 小时后热熔成型产品（厚度为 3 毫米）的黄色指数等于或小于 6，以及其生产方法。 在式 (1)中，Rf1、Rf2、Rf3 和 Rf4 分别独立地为氟原子、具有 1 至 7 个碳原子的直链全氟烷基、具有 3 至 7 个碳原子的支链全氟烷基或具有 3 至 7 个碳原子的环状全氟烷基组成的基团之一。全氟烷基可以具有一个乙氧基。此外，Rf1、Rf2、Rf3 和 Rf4 可彼此相连，形成一个具有 4 个或更多和 8 个或更少碳原子的环，该环可包括一个乙醚氧原子。
• FLUORORESIN, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING FLUORORESIN PARTICLES
  申请人：Tosoh Corporation

  公开号：EP3865521A1

  公开（公告）日：2021-08-18

  The present invention relates to a fluororesin including a residue unit represented by a following general formula (1) and having a haze value equal to or less than 2% of a heat-press molded product (thickness 1 mm) with a small haze value of a melt-molded product and a method for producing the same. In the formula (1), Rf1, Rf2, Rf3 and Rf4 each independently represent one of the groups consisting of a fluorine atom, a linear perfluoroalkyl group having 1 to 7 carbon atoms, a branched perfluoroalkyl group having 3 to 7 carbon atoms, and a cyclic perfluoroalkyl group having 3 to 7 carbon atoms, the perfluoroalkyl group may have an ethereal oxygen atom, Rf1, Rf2, Rf3 and Rf4 may be linked to each other to form a ring having 4 or more and 8 or less carbon atoms, and the ring may include an ethereal oxygen atom. The present invention further relates to a method for producing fluororesin particles that each include a fluorine-containing aliphatic ring structure. The method comprises a precipitation step of lowering a solution temperature of a fluororesin (A) solution in which a fluororesin (A) including a fluorine-containing aliphatic ring structure is dissolved in a solvent (B), to precipitate particles of the fluororesin (A). The method is excelling in productivity and making it possible to remove foreign matter.

  本发明涉及一种包括由以下通式（1）表示的残留单元、雾度值等于或小于 2% 的热压成型产品（厚度为 1 毫米）和雾度值较小的熔融成型产品的氟树脂，以及生产这种氟树脂的方法。 在式 (1)中，Rf1、Rf2、Rf3 和 Rf4 各自独立地代表由以下基团组成的基团之一：氟原子、具有 1 至 7 个碳原子的直链全氟烷基、具有 3 至 7 个碳原子的支链全氟烷基、和具有 3 至 7 个碳原子的环状全氟烷基，全氟烷基可具有一个乙氧基，Rf1、Rf2、Rf3 和 Rf4 可相互连接以形成具有 4 个或更多和 8 个或更少碳原子的环，该环可包括一个乙氧基。本发明还涉及一种生产氟树脂颗粒的方法，这些氟树脂颗粒各包括一个含氟脂肪族环结构。该方法包括一个沉淀步骤，即降低氟树脂（A）溶液的溶液温度，在该溶液中，包括含氟脂肪族环结构的氟树脂（A）溶解在溶剂（B）中，以沉淀氟树脂（A）颗粒。该方法不仅生产效率高，而且可以去除异物。