2-菲甲醛 | 26842-00-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 2-菲甲醛
• 中文别名: 菲-2-甲醛
• 英文名称: 2-Formyl-phenanthren
• 英文别名: phenanthrene-2-carboxaldehyde；phenanthrene-2-carbaldehyde
• CAS: 26842-00-2
• 化学式: C₁₅H₁₀O
• 分子量: 206.244
• InChiKey: GKROKAVBUIADBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2912299000

反应信息

• 作为反应物：
  描述：

  2-菲甲醛 在 盐酸 、 氢氧化钾 、 乙醇 、 溶剂黄146 作用下， 生成 2-[2]phenanthryl-ethylamine
  参考文献：
  名称：

  Occupational stress in universities: Staff perceptions of the causes, consequences and moderators of stress

  摘要：

  In recent years, the Australian university sector has undergone large-scale organizational change, including restructuring, downsizing and government funding cuts. At the same tune, research front across the globe reports an alarming increase in the occupational stress experienced by university staff. We report on the first phase of a longitudinal investigation of occupational stress. A total of 22 focus groups were conducted with a representative sample of 178 academic and general staff from 15 Australian universities. The groups focused on understanding staff's experience of occupational stress, and perceptions of the sources, consequences and moderators of stress. Both general and academic staff reported a dramatic increase in stress during the previous 5 years. As a group, academic staff reported higher levels of stress than general staff. Five major or sources of stress were identified including: insufficient funding and resources; work overload; poor management practice; job insecurity; and insufficient recognition and reward. The majority of groups reported that job-related stress was having a deleterious impact on their professional work and personal welfare. Aspects of the work environment (support front co-workers and management, recognition and achievement, high morale, flexible working conditions), and personal coping strategies (stress management techniques, work/non-work balance, tight role boundaries and lowering standards), were reported to help staff cope with stress. The findings provide a timely insight into the experience of stress within universities.

  DOI：

  10.1080/02678370117944
• 作为产物：
  描述：

  菲 在 sodium hypochlorite 、 lithium aluminium tetrahydride 、 三氯化铝 、 三氟化硼 、 pyridinium chlorochromate 作用下， 以 乙醚 、 二氯甲烷 、 水 、 硝基苯 为溶剂， 反应 41.0h， 生成 2-菲甲醛
  参考文献：
  名称：

  Brown, John W.; Byron, David J.; Fawcett, Linda A., Journal of the Chemical Society. Perkin transactions II, 1986, p. 1593 - 1596

  摘要：

  DOI：

文献信息

• Linear Conjugated Systems Bearing Aromatic Terminal Groups. V. Syntheses and Electronic Spectra of 2,2′-, 3,3′-, and 9,9′-Diphenanthrylpoly-ynes
  作者：Shuzo Akiyama、Masazumi Nakagawa

  DOI：10.1246/bcsj.44.2237

  日期：1971.8

  2,2′-, 3,3′-, and 9,9′-Diphenanthrylpoly-ynes (Vn, VIn, and VIIn, n=1–6) were synthesized and their electronic spectra were measured. It was found that the longest-wavelength absorption maxima (λmax) in the spectra of each series of the diphenanthrylpoly-ynes (Vn, VIn and VIIn) shift linearly with the xth power of the number of acetylenic bond (n), [λmax∝nx], being x=1.3 for Vn and x=1.4 for VIn and

  合成了 2,2'-、3,3'- 和 9,9'-二菲基多炔（Vn、VIn 和 VIIn，n=1-6）并测量了它们的电子光谱。发现各系列二菲基聚炔（Vn、VIn 和 VIIn）的光谱中最长波长吸收最大值（λmax）随炔键数（n）的 x 次方线性移动，[λmax∝ nx]，对于 Vn，x=1.3，对于 VIn 和 VIIn，x=1.4。
• 一种2-芳基苯并噻唑化合物的制备方法
  申请人：东华理工大学

  公开号：CN111072594B

  公开（公告）日：2023-05-05

  本发明公开了一种2‑芳基苯并噻唑化合物的制备方法，该方法包含：将反应底物2‑氨基苯硫酚与酮酸(或醛)加入深共融溶剂中，在60℃～90℃油浴锅中磁力搅拌，待反应结束后进行后处理，得到2‑芳基苯并噻唑化合物；其中，深共融溶剂为反应溶剂，无需其它催化剂。本发明方法操作简单，反应条件温和，反应高效，原子经济性高，副产物少，反应过程绿色环保，具有推广应用价值。
• Construction of polyaromatics via photocyclization of 2-(fur-3-yl)ethenylarenes, using a 3-furyl group as an isopropenyl equivalent synthon
  作者：Ying-Zhe Chen、Ching-Wen Ni、Fu-Lin Teng、Yi-Shun Ding、Tunng-Hsien Lee、Jinn-Hsuan Ho

  DOI：10.1016/j.tet.2014.01.035

  日期：2014.3

  The construction of different types of substituted arenes was demonstrated through the photocyclization of 2-(fur-3-yl)ethenylarenes using a 3-furyl group as an isopropenyl equivalent synthon in the photocyclization reaction. The furan portion of the photocyclization intermediate could be fragmented via a base-induced elimination reaction to yield a series of substituted polyaromatics, including naphthalene

  通过在光环化反应中使用3-呋喃基作为异丙烯基当量合成子，通过2-（呋喃基-3-基）乙烯基芳烃的光环化，证明了不同类型取代的芳烃的构建。可以通过碱诱导的消除反应使光环化中间体的呋喃部分断裂，以产生一系列取代的聚芳族化合物，包括萘，苯并呋喃，苯并噻吩，菲，菲、,和三亚苯基。使用不同的试剂，该方法使得可以在这些芳烃的特定位置处引入甲基或2-羟乙基作为取代基。
• A new procedure for formylation of less active aromatics
  作者：Antonio García Martínez、Roberto Martínez Alvarez、José Osío Barcina、S. de la Moya Cerero、E. Teso Vilar、A. García Fraile、Michael Hanack、L. R. Subramanian

  DOI：10.1039/c39900001571

  日期：——

  The formylation of aromatic compounds with trifluoromethanesulphonic anhydride/dimethylformamide complex 2 takes place easily as compared to the normal Vilsmeier–Haack reaction.

  与正常的Vilsmeier-Haack反应相比，芳族化合物与三氟甲磺酸酐/二甲基甲酰胺络合物2的甲酰化反应容易进行。
• 3-Amino-2-benzyl-1-phenylpropane derivatives
  申请人：——

  公开号：US20020161262A1

  公开（公告）日：2002-10-31

  Substituted 3-amino-2-benzyl-1-phenlypropane derivatives, methods for preparing them, pharmaceutical compositions containing them, and methods of using them to treat various medical conditions.

  替代3-氨基-2-苄基-1-苯丙烷衍生物，制备它们的方法，含有它们的药用组合物，以及使用它们治疗各种医疗状况的方法。