7-Oxabicyclo[4.2.0]oct-2-en-8-one | 65656-92-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 7-Oxabicyclo[4.2.0]oct-2-en-8-one
• CAS: 65656-92-0
• 化学式: C₇H₈O₂
• 分子量: 124.14
• InChiKey: QWNNORORNKLPEF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  7-Oxabicyclo[4.2.0]oct-2-en-8-one 、 氢化铝锂 生成 [6-(4-methylphenyl)sulfonyloxycyclohex-2-en-1-yl]methyl 4-methylbenzenesulfonate
  参考文献：
  名称：

  ANNIS G. D.; LEY S. V.; SELF C. R.; SIVARAMAKRIEHNAN R., J. CHEM. SOC. PERKIN TRANS., 1981, PART 1, NO 1, 270-277

  摘要：

  DOI：

文献信息

• METAL-ORGANIC FRAMEWORK CATALYSTS, AND USES THEREOF
  申请人：Novomer, Inc.

  公开号：US20210277028A1

  公开（公告）日：2021-09-09

  Provided herein are metal-organic frameworks having a repeating core structure that generally includes a linker coordinated to a secondary building unit through O-metal-O bonds. The linkers create a framework with a plurality of pores, where a cobalt carbonyl moiety occupies at least a portion of the plurality of pores. Provided are also methods of making such metal-organic frameworks via a solvothermal reaction. The metal-organic frameworks are suitable for use in carbonylation reactions, such as carbonylation of epoxides. The metal-organic frameworks may be used for producing acrylic acid from ethylene oxide and carbon monoxide on an industrial scale. The production may involve various unit operations, including for example a beta-propiolactone production system configured to produce beta-propiolactone from ethylene oxide and carbon monoxide; a polypropiolactone production system configured to produce polypropiolactone from beta-propiolactone; and an acrylic acid production system configured to produce acrylic acid with a high purity by thermolysis of polypropiolactone.
• POLYLACTONE FOAMS AND METHODS OF MAKING THE SAME
  申请人：Novomer, Inc.

  公开号：US20210324168A1

  公开（公告）日：2021-10-21

  The present invention is directed to compositions comprising polylactone melt, extrudate, and processes for producing a foam. In exemplary embodiments of the present invention, the processes comprise: heating a polylactone composition containing a biobased polylactone in a reaction vessel; and subjecting the polylactone composition to molding to give a foamed structure.
• ANNIS G. D.; LEY S. V.; SELF C. R.; SIVARAMAKRIEHNAN R., J. CHEM. SOC. PERKIN TRANS., 1981, PART 1, NO 1, 270-277
  作者：ANNIS G. D.、 LEY S. V.、 SELF C. R.、 SIVARAMAKRIEHNAN R.

  DOI：——

  日期：——