1-(2-Oxo-2-{2-[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]hydrazinyl}ethyl)pyridin-1-ium chloride | 10439-64-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(2-Oxo-2-{2-[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]hydrazinyl}ethyl)pyridin-1-ium chloride
• 英文别名: N-[(2-hydroxyphenyl)methylideneamino]-2-pyridin-1-ium-1-ylacetamide;chloride
• CAS: 10439-64-2
• 化学式: C₁₄H₁₄N₃O₂*Cl
• 分子量: 291.737
• InChiKey: OZTPEXSEUNQQDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.17
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  65.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-(2-Oxo-2-{2-[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]hydrazinyl}ethyl)pyridin-1-ium chloride 、 zinc diacetate 以 乙醇 为溶剂， 生成 [zinc(salicylidene Girard-P hydrazone)(H2O)]Cl
  参考文献：
  名称：

  Potentiometric and thermal conductimetric studies on salicylidene Girard-P hydrazone complexes of divalent Co, Ni, Cu and Zn salts

  摘要：

  Salicylidene Girard-P hydrazone [H(2)L]Cl reacts with divalent cobalt, nickel, copper and zinc ions to form mono-ligand complexes of the type [ML . H2O]Cl . nH(2)O and [(CuL)(2)]Cl-2. The formation constants of the complexes ML were determined in 50% (v/v) aqueous ethanol solution at an ionic strength l=0.1 M KCl and at 25+/-0.1 degrees C. The solid complexes and the ligand were subjected to differential thermal analysis and the DC electrical conductivities were measured at varying temperatures. The results obtained were explained and discussed in terms of the proposed semiconductive behaviour of the complexes and the probable occurrence of a phase transition. The activation energies (Delta E) were calculated for the ligand and the complexes; that of the ligand was higher than those of the complexes.

  DOI：

  10.1007/bf02547448

文献信息

• Wang, Xin; Zhang, Xiao Min; Liu, Hai Xin, Inorganica Chimica Acta, 1994, vol. 223, p. 193 - 197
  作者：Wang, Xin、Zhang, Xiao Min、Liu, Hai Xin

  DOI：——

  日期：——
• Magnetic properties of copper(II) complexes with some hydrazones of substituted salicylaldehydes
  作者：L. D. Popov、Yu. P. Tupolova、S. I. Levchenkov、V. V. Lukov、V. A. Kogan

  DOI：10.1134/s1070328407030098

  日期：2007.3

  A series of novel mono- and binuclear copper(II) complexes with substituted salicylaldehyde acyl-hydrazones H2L of the formula CuL center dot xH2O (x = 0 and 1) and [Cu(HL)](ClO4)(CH3OH) were synthesized. The isolated dimeric complexes of copper acetate were found to exist as isomers with different bridging atoms. In dimers showing a superexchange between the paramagnetic centers through bridging phenoxide O atoms, the anti ferromagnetic exchange couplings were much stronger than those in complexes with bridging O atoms of the a-oxyazine fragment.
• Potentiometric and thermal conductimetric studies on salicylidene Girard-P hydrazone complexes of divalent Co, Ni, Cu and Zn salts
  作者：R. M. El-Bahnasawy

  DOI：10.1007/bf02547448

  日期：1995.12

  Salicylidene Girard-P hydrazone [H(2)L]Cl reacts with divalent cobalt, nickel, copper and zinc ions to form mono-ligand complexes of the type [ML . H2O]Cl . nH(2)O and [(CuL)(2)]Cl-2. The formation constants of the complexes ML were determined in 50% (v/v) aqueous ethanol solution at an ionic strength l=0.1 M KCl and at 25+/-0.1 degrees C. The solid complexes and the ligand were subjected to differential thermal analysis and the DC electrical conductivities were measured at varying temperatures. The results obtained were explained and discussed in terms of the proposed semiconductive behaviour of the complexes and the probable occurrence of a phase transition. The activation energies (Delta E) were calculated for the ligand and the complexes; that of the ligand was higher than those of the complexes.