[zinc(salicylidene Girard-P hydrazone)(H2O)]Cl | 173928-76-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [zinc(salicylidene Girard-P hydrazone)(H2O)]Cl
• CAS: 173928-76-2
• 化学式: C₁₄H₁₄N₃O₃Zn*Cl
• 分子量: 373.126
• InChiKey: QOOWCFKAKAWHRI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-(2-Oxo-2-{2-[(E)-(6-oxocyclohexa-2,4-dien-1-ylidene)methyl]hydrazinyl}ethyl)pyridin-1-ium chloride 、 zinc diacetate 以 乙醇 为溶剂， 生成 [zinc(salicylidene Girard-P hydrazone)(H2O)]Cl
  参考文献：
  名称：

  Potentiometric and thermal conductimetric studies on salicylidene Girard-P hydrazone complexes of divalent Co, Ni, Cu and Zn salts

  摘要：

  Salicylidene Girard-P hydrazone [H(2)L]Cl reacts with divalent cobalt, nickel, copper and zinc ions to form mono-ligand complexes of the type [ML . H2O]Cl . nH(2)O and [(CuL)(2)]Cl-2. The formation constants of the complexes ML were determined in 50% (v/v) aqueous ethanol solution at an ionic strength l=0.1 M KCl and at 25+/-0.1 degrees C. The solid complexes and the ligand were subjected to differential thermal analysis and the DC electrical conductivities were measured at varying temperatures. The results obtained were explained and discussed in terms of the proposed semiconductive behaviour of the complexes and the probable occurrence of a phase transition. The activation energies (Delta E) were calculated for the ligand and the complexes; that of the ligand was higher than those of the complexes.

  DOI：

  10.1007/bf02547448