3,4-二乙基-3-己醇 | 19398-78-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 3,4-二乙基-3-己醇
• 中文别名: 3,4-二乙基-3-己醇,赤式+苏式
• 英文名称: 3,4-diethyl-3-hexanol
• 英文别名: 3,4-diethyl-hexan-3-ol；1.1.2.2-Tetraaethyl-aethylalkohol；3,4-Diaethyl-hexan-3-ol；3,4-diethylhexan-3-ol
• CAS: 19398-78-8
• 化学式: C₁₀H₂₂O
• 分子量: 158.284
• InChiKey: WKHFIEUDEJOTPQ-UHFFFAOYSA-N

物化性质

• 稳定性/保质期：
  常温常压下稳定，避免与氧化物接触。

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 危险类别码：
  R36/37/38
• 安全说明：
  S26

反应信息

• 作为反应物：
  描述：

  3,4-二乙基-3-己醇 在 草酸 作用下， 生成 3,4-diethyl-3-hexene
  参考文献：
  名称：

  Koch; Hilberath, Chemische Berichte, 1940, vol. 73, p. 1172

  摘要：

  DOI：
• 作为产物：
  描述：

  2-乙基丁酸乙酯 、 乙基溴化镁 在 乙醚 作用下， 生成 3,4-二乙基-3-己醇
  参考文献：
  名称：

  Koch; Hilberath, Chemische Berichte, 1940, vol. 73, p. 1172

  摘要：

  DOI：

文献信息

• Iso-olefin production and etherification process
  申请人：CHEVRON RESEARCH AND TECHNOLOGY COMPANY

  公开号：EP0534142A1

  公开（公告）日：1993-03-31

  A process for increasing iso-butylene and iso-pentene yield from a refinery naptha comprising contacting a olefinic naptha stream comprising C₅-C₉ olefins with a low acidic crystalline silicate catalyst at a pressure of less than 300 psig and a temperature of between about 500 to about 900 F to produce a product stream rich in iso-butylene and iso-pentene.

  一种从炼油烯烃中提高异丁烯和异戊烯产量的工艺，包括在压力小于 300 psig 和温度介于约 500 至约 900 F 之间的条件下，将包含 C₅-C₉ 烯烃的烯烃烯烃流与低酸性结晶硅酸盐催化剂接触，以产生富含异丁烯和异戊烯的产品流。
• Tischtschenko, Zhurnal Obshchei Khimii, 1938, vol. 8, p. 1242
  作者：Tischtschenko

  DOI：——

  日期：——
• Secondary Organic Aerosol Formation via the Isolation of Individual Reactive Intermediates: Role of Alkoxy Radical Structure
  作者：Anthony J. Carrasquillo、James F. Hunter、Kelly E. Daumit、Jesse H. Kroll

  DOI：10.1021/jp506562r

  日期：2014.9.25

  The study of the chemistry underlying secondary organic aerosol (SOA) formation is complicated by the large number of reaction pathways and oxidation generations available to a given precursor species. Here we simplify such complexity to that of a single alkoxy radical (RO), by forming SOA via the direct photolysis of alkyl nitrite (RONO) isomers. Chamber experiments were conducted with 11 C10 RONO isomers to determine how the position of the radical center and branching of the carbon skeleton influences SOA formation. SOA yields served as a probe of RO reactivity, with lower yields indicating that fragmentation reactions dominate and higher yields suggesting the predominance of RO isomerization. The largest yields were from straight-chain isomers, particularly those with radical centers located toward the terminus of the molecule. Trends in SOA yields can be explained in terms of two major effects: (1) the relative importance of isomerization and fragmentation reactions, which control the distribution of products, and (2) differences in volatility among the various isomeric products formed. Yields from branched isomers, which were low but variable, provide insight into the degree of fragmentation of the alkoxy radicals; in the case of the two β-substituted alkoxy radicals, fragmentation appears to occur to a greater extent than predicted by structure-activity relationships. Our results highlight how subtle differences in alkoxy radical structure can have major impacts on product yields and SOA formation.
• METHOD FOR CONTROLLING MULTISTAGE REFORMING PROCESS TO GIVE HIGH OCTANE BARREL PER CALENDAR DAY THROUGHPUT
  申请人：CHEVRON RESEARCH AND TECHNOLOGY COMPANY

  公开号：EP0516745A1

  公开（公告）日：1992-12-09
• DEHYDROCYCLIZATION OR CATALYTIC REFORMING USING SULFUR TOLERANT ZEOLITE CATALYST
  申请人：CHEVRON RESEARCH AND TECHNOLOGY COMPANY

  公开号：EP0524956A1

  公开（公告）日：1993-02-03

表征谱图