(11-boranuidyl-8,11-ditert-butyl-2,5,14,17-tetraoxa-8,11-diphosphoniabicyclo[16.4.0]docosa-1(22),18,20-trien-8-yl)boranuide | 1423013-26-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (11-boranuidyl-8,11-ditert-butyl-2,5,14,17-tetraoxa-8,11-diphosphoniabicyclo[16.4.0]docosa-1(22),18,20-trien-8-yl)boranuide
• CAS: 1423013-26-6；1423065-50-2；1423065-51-3
• 化学式: C₂₄H₄₈B₂O₄P₂
• 分子量: 484.212
• InChiKey: QARXSJVEXQFEEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (11-boranuidyl-8,11-ditert-butyl-2,5,14,17-tetraoxa-8,11-diphosphoniabicyclo[16.4.0]docosa-1(22),18,20-trien-8-yl)boranuide 在 吗啉 作用下， 以 甲苯 为溶剂， 反应 48.0h， 以100%的产率得到
  参考文献：
  名称：

  Synthesis of Enantiopure P-Stereogenic Diphosphacrowns using P-Stereogenic Secondary Phosphines

  摘要：

  A new synthetic route to enantiopure P-stereogenic benzodiphosphacrowns using a P-stereogenic secondary bisphosphine as the key building block is reported. Syntheses of the enantiomer and P-stereogenic crowns with various ring structures, as well as deboranation of the crown compounds and subsequent reaction with a platinum complex, are described.

  DOI：

  10.1021/jo302748x
• 作为产物：
  描述：

  1,2-bis[2-(2-hydroxyethoxy)ethoxy]benzene 在 正丁基锂 、 sodium hydroxide 作用下， 以 四氢呋喃 、 正己烷 、 水 为溶剂， 反应 1.0h， 生成 (11-boranuidyl-8,11-ditert-butyl-2,5,14,17-tetraoxa-8,11-diphosphoniabicyclo[16.4.0]docosa-1(22),18,20-trien-8-yl)boranuide
  参考文献：
  名称：

  Synthesis of Enantiopure P-Stereogenic Diphosphacrowns using P-Stereogenic Secondary Phosphines

  摘要：

  A new synthetic route to enantiopure P-stereogenic benzodiphosphacrowns using a P-stereogenic secondary bisphosphine as the key building block is reported. Syntheses of the enantiomer and P-stereogenic crowns with various ring structures, as well as deboranation of the crown compounds and subsequent reaction with a platinum complex, are described.

  DOI：

  10.1021/jo302748x

文献信息

• Synthesis of Enantiopure P-Stereogenic Diphosphacrowns using P-Stereogenic Secondary Phosphines
  作者：Yasuhiro Morisaki、Ryosuke Kato、Yoshiki Chujo

  DOI：10.1021/jo302748x

  日期：2013.3.15

  A new synthetic route to enantiopure P-stereogenic benzodiphosphacrowns using a P-stereogenic secondary bisphosphine as the key building block is reported. Syntheses of the enantiomer and P-stereogenic crowns with various ring structures, as well as deboranation of the crown compounds and subsequent reaction with a platinum complex, are described.