2-Methyl-acrylic acid 2,2,5-trimethyl-[1,3]dioxan-5-ylmethyl ester | 7299-81-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Methyl-acrylic acid 2,2,5-trimethyl-[1,3]dioxan-5-ylmethyl ester
• 英文别名: (2,2,5-Trimethyl-1,3-dioxan-5-yl)methyl 2-methylprop-2-enoate
• CAS: 7299-81-2
• 化学式: C₁₂H₂₀O₄
• 分子量: 228.288
• InChiKey: ZIDIOHIXUSAZJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-Methyl-acrylic acid 2,2,5-trimethyl-[1,3]dioxan-5-ylmethyl ester 生成 2,2-bis(hydroxymethyl)propyl methacrylate
  参考文献：
  名称：

  新型有机官能环磷腈衍生物

  摘要：

  摘要 甲基丙烯酰基磷腈 N3P3Cl5O(CHR)x(CHR')yOC(O)CMe=CH2 (x=y=1,2, R=R'=H; x=1, R=Me) 的合理设计、合成和聚合, y=1, R'=H; x=1, R=H, y=1, R'=Me)。以5-壬二烯-2-甲醇盐和N3P3Cl5为原料制备了另一种新型链烯氧基衍生物。报道了具有甲基丙烯酸酯或受保护羟基的螺环衍生物的制备。已经制备了环磷腈的各种功能化二茂铁衍生物，特别关注 N3P3Cl6-n(NMeCH2C5H4FeC5H5)n(n=1,2,3,4) 系列的合成和电化学表征。

  DOI：

  10.1080/10426509608545095
• 作为产物：
  描述：

  1,1,1-三(羟甲基)乙烷 生成 2-Methyl-acrylic acid 2,2,5-trimethyl-[1,3]dioxan-5-ylmethyl ester
  参考文献：
  名称：

  新型有机官能环磷腈衍生物

  摘要：

  摘要 甲基丙烯酰基磷腈 N3P3Cl5O(CHR)x(CHR')yOC(O)CMe=CH2 (x=y=1,2, R=R'=H; x=1, R=Me) 的合理设计、合成和聚合, y=1, R'=H; x=1, R=H, y=1, R'=Me)。以5-壬二烯-2-甲醇盐和N3P3Cl5为原料制备了另一种新型链烯氧基衍生物。报道了具有甲基丙烯酸酯或受保护羟基的螺环衍生物的制备。已经制备了环磷腈的各种功能化二茂铁衍生物，特别关注 N3P3Cl6-n(NMeCH2C5H4FeC5H5)n(n=1,2,3,4) 系列的合成和电化学表征。

  DOI：

  10.1080/10426509608545095

文献信息

• Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate
  申请人：Fujifilm Corporation

  公开号：EP1803784A2

  公开（公告）日：2007-07-04

  The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B') an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.

  本发明提供了一种墨水组合物，它至少具有(A)聚合引发剂，(B)具有 1，3-二氧戊环骨架或 1，3-二氧六环骨架的(甲基)丙烯酸酯或酰胺，或(B')具有 1，3-二酮结构的(甲基)丙烯酸酯或酰胺，以及(C)着色剂。本发明进一步提供了一种喷墨记录方法和一种平面印刷板的制作方法，其中每种方法都至少包括：(I) 将墨水组合物喷射到亲水性支撑物上；(II) 用活性辐射照射喷射出的墨水组合物，使墨水组合物固化，从而在亲水性支撑物上形成疏水性图像区域。此外，本发明还提供了一种由该方法形成的平版印刷板。
• Inkjet recording composition, inkjet recording method, method for producing planographic printing plate, and planographic printing plate
  申请人：Fujifilm Corporation

  公开号：EP1803784B1

  公开（公告）日：2011-08-03
• INK COMPOSITION, INKJET RECORDING METHOD, PRINTED MATERIAL, METHOD FOR PRODUCING PLANOGRAPHIC PRINTING PLATE, AND PLANOGRAPHIC PRINTING PLATE
  申请人：Nakamura Ippei

  公开号：US20100298494A1

  公开（公告）日：2010-11-25

  The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B′) an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.
• US7794918B2
  申请人：——

  公开号：US7794918B2

  公开（公告）日：2010-09-14
• US8211623B2
  申请人：——

  公开号：US8211623B2

  公开（公告）日：2012-07-03