3,6-二氯-9-甲基咔唑 | 23999-51-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: 3,6-二氯-9-甲基咔唑
• 英文名称: 3,6-dichloro-N-methylcarbazole
• 英文别名: SJ000120619-1；3,6-dichloro-9-methyl-carbazole；3,6-Dichlor-9-methyl-carbazol；3,6-Dichlor-9-methylcarbazol；3,6-Dichloro-9-methylcarbazole
• CAS: 23999-51-1
• 化学式: C₁₃H₉Cl₂N
• mdl: MFCD00218273
• 分子量: 250.127
• InChiKey: VAHVPQYDPPVHKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2933990090

反应信息

• 作为产物：
  描述：

  3-氯-9-甲基咔唑 在 五氯化磷 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 0.08h， 以58%的产率得到3,6-二氯-9-甲基咔唑
  参考文献：
  名称：

  A convenient method for obtaining 3-chloro- and 3,6-dichlorocarbazoles

  摘要：

  DOI：

  10.1007/bf00506069

文献信息

• On the synthesis and isolation of chlorocarbazoles obtained by chlorination of<i>N</i>-substituted carbazoles
  作者：Sergio M. Bonesi、Rosa Erra-Balsells

  DOI：10.1002/jhet.5570340328

  日期：1997.5

  4b, 5a, 5b, 5c, 5d and 5e. Some of them are described for the first time. By using semiempirical PM3 method theoretical substituent effects on the chlorinating reaction are calculated. A chlorination mechanism of carbazoles and N-substituted carbazoles are compared.

  合成了N-甲基咔唑（1），N-苯基咔唑（2），N-乙酰咔唑（3），N-苯甲酰基咔唑（4）和2-甲氧基-N-甲基咔唑的氯衍生物。它们是化合物1a，1b，1c，1d，1e，2a，2b，3a，3b，3c，3d，4a，4b，5a，5b，5c，5d和5e。其中一些是第一次描述。通过使用半经验PM3方法，计算了理论上的取代基对氯化反应的影响。比较了咔唑和N-取代咔唑的氯化机理。
• NOVEL TRIARYLAMINE POLYMER, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF
  申请人：Tosoh Corporation

  公开号：EP1528074A1

  公开（公告）日：2005-05-04

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6 and Ar7 which are independent of one another, is an unsubstituted or substituted C6-60 aromatic group, Ar1 and Ar2 are the same or different, Ar3 and Ar4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided:

  本发明的目的是提供一种新型三芳基胺聚合物，该聚合物具有优异的溶解性和成膜性，并具有更好的热稳定性；提供一种简单的生产工艺；以及提供一种使用该聚合物的电子元件。 本发明提供了由下式（1）代表的三芳基胺聚合物（其中，Ar1、Ar2、Ar3、Ar4、Ar5、Ar6 和 Ar7 中的每一个彼此独立，是未取代或取代的 C6-60 芳族基团，Ar1 和 Ar2 相同或不同，Ar3 和 Ar4 相同或不同，且 m 是至少 1 的整数）、其生产工艺以及使用该聚合物的电子元件：
• Novel triarylamine polymer, process for its production and its use
  申请人：TOSOH CORPORATION

  公开号：EP2327739A1

  公开（公告）日：2011-06-01

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6 and Ar7 which are independent of one another, is an unsubstituted or substituted C6-60 aromatic group, Ar1 and Ar2 are the same or different, Ar3 and Ar4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided:

  本发明的目的是提供一种新型三芳基胺聚合物，该聚合物具有优异的溶解性和成膜性，并具有更好的热稳定性；提供一种简单的生产工艺；以及提供一种使用该聚合物的电子元件。 本发明提供了由下式（1）代表的三芳基胺聚合物（其中，Ar1、Ar2、Ar3、Ar4、Ar5、Ar6 和 Ar7 中的每一个彼此独立，是未取代或取代的 C6-60 芳族基团，Ar1 和 Ar2 相同或不同，Ar3 和 Ar4 相同或不同，且 m 是至少 1 的整数）、其生产工艺以及使用该聚合物的电子元件：
• Antimicrobial compounds, compositions and methods of use thereof
  申请人：Wisconsin Alumni Research Foundation

  公开号：US10314816B2

  公开（公告）日：2019-06-11

  Described herein are antimicrobial compounds identified via a high-throughput inhibitor screen of the in vitro activity of MipZ, which is an ATPase that regulates division site placement in Caulobacter crescentus. The compounds and their analogs are active against bacterial membranes and thus represent a novel class of antimicrobial compounds. The antimicrobial compounds are effective against both actively growing bacterial cells as well as bacterial cells in the stationary phase. The antimicrobial compounds are also effective against bacteria in biofilms.

  本文介绍的抗菌化合物是通过对 MipZ 的体外活性进行高通量抑制剂筛选而发现的，MipZ 是一种 ATP 酶，可调节新月杆菌分裂位点的位置。这些化合物及其类似物对细菌膜具有活性，因此是一类新型抗菌化合物。这些抗菌化合物对活跃生长的细菌细胞和处于静止期的细菌细胞都有效。这些抗菌化合物对生物膜中的细菌也有效。
• Organic electroluminescent device
  申请人：UDC IRELAND LIMITED

  公开号：US11411185B2

  公开（公告）日：2022-08-09

  An organic electroluminescent device includes a pair of electrodes; and an organic layer between the pair of electrodes, which includes a light-emitting layer, wherein the organic layer contains a compound represented by the following formula (I); and the light-emitting layer contains a iridium complex phosphorescent material: wherein R1, R2, R3, R4, R5, R6, R7 and R8 each represents a hydrogen atom or a substituent, and contiguous substituents of R1 to R8 may be bonded to each other to form a condensed ring; R9 represents an alkyl group, an alkenyl group, an aryl group, a hetero-aryl group, or a silyl group, and each of which group may be substituted with a substituent; and at least one of R1 to R9 represents a deuterium atom or a substituent containing a deuterium atom.

  一种有机电致发光装置包括一对电极；以及位于这对电极之间的有机层，其中包括发光层，有机层含有下式（I）所代表的化合物；发光层含有铱络合物磷光材料： 其中 R1、R2、R3、R4、R5、R6、R7 和 R8 各自代表氢原子或取代基，R1 至 R8 的连续取代基可相互键合以形成缩合环；R9 代表烷基、烯基、芳基、杂芳基或硅烷基，其中每个基团可被取代基取代；以及 R1 至 R9 中至少有一个代表氘原子或含有氘原子的取代基。