2-Hexyl-2-methyl-1,3-dioxacyclohexan | 5702-46-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Hexyl-2-methyl-1,3-dioxacyclohexan
• 英文别名: 2-hexyl-2-methyl-[1,3]dioxane；2-Hexyl-2-methyl-[1,3]dioxan；1,3-Dioxane, 2-hexyl-2-methyl-；2-hexyl-2-methyl-1,3-dioxane
• CAS: 5702-46-5
• 化学式: C₁₁H₂₂O₂
• 分子量: 186.294
• InChiKey: YBSCCLQQTAAJDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Hexyl-2-methyl-1,3-dioxacyclohexan 在 三氟甲磺酸三甲基硅酯 、 dimethyl sulfide borane 作用下， 以 二氯甲烷 为溶剂， 以53%的产率得到3-(1-Methyl-heptyloxy)-propan-1-ol
  参考文献：
  名称：

  Reduction of activated ketals with borane-dimethyl sulphide

  摘要：

  Borane-Dimethyl sulphide reduces ketals activated with TMSOTf at -78-degrees-C in dichloromethane. The scope and selectivity of the reagent has been investigated.

  DOI：

  10.1016/s0040-4039(00)74497-2
• 作为产物：
  描述：

  2-甲基-1,3-二恶烷 、 乙烯 生成 2-Hexyl-2-methyl-1,3-dioxacyclohexan
  参考文献：
  名称：

  NAYANOV V. P.; ZORIN V. V.; ZLOTSKIJ S. S.; TERENTEV A. B.; RAXMANKULOV D+, ZH. PRIKL. XIMII , 1976, 49, HO 10, 2350-2352

  摘要：

  DOI：

文献信息

• Salmi; Rannikko, Chemische Berichte, 1939, vol. 72, p. 600,602
  作者：Salmi、Rannikko

  DOI：——

  日期：——
• SOLID CATALYST FOR OLEFIN POLYMERIZATION AND PROCESS FOR PRODUCING OLEFIN POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20130072648A1

  公开（公告）日：2013-03-21

  A solid catalyst for olefin polymerization and a process for producing an olefin polymer are provided. The polymer has a small content of a component which is dissolved out into a low temperature organic solvent, such as a low-molecular weight component and an amorphous component. The solid catalyst is obtained by bringing a solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an aliphatic carboxylate; an organoaluminum compound; and a compound represented by formula (I) into contact with each other: wherein R 1 is a hydrocarbyl group having 1 to 10 carbon atoms, R 2 is a hydrogen atom, a halogen atom or a hydrocarbyl group having 1 to 16 carbon atoms, and the R 1 the R 2 groups are independently the same or different, and the respective R 1 groups and R 2 groups may be joined with each other to form a ring.
• Reduction of activated ketals with borane-dimethyl sulphide
  作者：Roger Hunter、Birgit Bartels、Joseph P. Michael

  DOI：10.1016/s0040-4039(00)74497-2

  日期：1991.2

  Borane-Dimethyl sulphide reduces ketals activated with TMSOTf at -78-degrees-C in dichloromethane. The scope and selectivity of the reagent has been investigated.
• NAYANOV V. P.; ZORIN V. V.; ZLOTSKIJ S. S.; TERENTEV A. B.; RAXMANKULOV D+, ZH. PRIKL. XIMII <ZRKN-BC>, 1976, 49, HO 10, 2350-2352
  作者：NAYANOV V. P.、 ZORIN V. V.、 ZLOTSKIJ S. S.、 TERENTEV A. B.、 RAXMANKULOV D+

  DOI：——

  日期：——