2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-mannopyranoside | 120331-62-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-mannopyranoside
• 英文别名: 2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside；[(2R,3R,4S,5S,6S)-3,4,5-triacetyloxy-6-[(2S,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]sulfanyloxan-2-yl]methyl acetate
• CAS: 120331-62-6
• 化学式: C₂₈H₃₈O₁₈S
• 分子量: 694.665
• InChiKey: VJUMXLNMLSEYRN-YFWBNXDHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  47
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  254
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为产物：
  描述：

  1-硫代-b-D-葡萄糖四乙酸酯 、 2,3,4,6-四-O-乙酰基-1-溴-Alpha-D-甘露糖 生成 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-mannopyranoside
  参考文献：
  名称：

  CHRETIEN, FRANCOISE;DI, CESARE PIERRE;GROSS, BERNARD, J. CHEM. SOC. PERKIN TRANS. PT 1,(1988) N2, C. 3297-3300

  摘要：

  DOI：

文献信息

• A facile preparation of trehalose analogues: 1,1-thiodisaccharides
  作者：Goreti Ribeiro Morais、Andrew J. Humphrey、Robert A. Falconer

  DOI：10.1016/j.carres.2009.03.017

  日期：2009.5

  The synthesis of 1,1-thiodisaccharide trehalose analogues in good to excellent yields by a Lewis acid (BF3 center dot Et2O)-catalysed coupling of sugar per-O-acetate with thiosugar is described. The reactivity of different sugar per-O-acetates and thiosugars is explored. (C) 2009 Elsevier Ltd. All rights reserved.
• Chretien, Francoise; Cesare, Pierre Di; Gross, Bernard, Journal of the Chemical Society. Perkin transactions I, 1988, p. 3297 - 3300
  作者：Chretien, Francoise、Cesare, Pierre Di、Gross, Bernard

  DOI：——

  日期：——
• CHRETIEN, FRANCOISE;DI, CESARE PIERRE;GROSS, BERNARD, J. CHEM. SOC. PERKIN TRANS. PT 1,(1988) N2, C. 3297-3300
  作者：CHRETIEN, FRANCOISE、DI, CESARE PIERRE、GROSS, BERNARD

  DOI：——

  日期：——