3-ethoxy-1,1,1-trifluoro-2-methyl-propan-2-ol | 336-88-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-ethoxy-1,1,1-trifluoro-2-methyl-propan-2-ol
• 英文别名: 3-Aethoxy-1,1,1-trifluor-2-methyl-propan-2-ol；3-Ethoxy-1,1,1-trifluoro-2-methylpropan-2-ol
• CAS: 336-88-9
• 化学式: C₆H₁₁F₃O₂
• 分子量: 172.147
• InChiKey: OQTBZGOTLAHFSD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-methyl-2-(trifluoromethyl)oxirane 、 sodium ethanolate 在 乙醇 作用下， 生成 3-ethoxy-1,1,1-trifluoro-2-methyl-propan-2-ol
  参考文献：
  名称：

  The Ethanolysis of 1,1,1-Trifluoro-2,3-epoxybutane and 2-Methyl-1,1,1-trifluoro-2,3-epoxypropane

  摘要：

  DOI：

  10.1021/ja01597a052

文献信息

• ORGANOANTIMONY COMPOUND, PROCESS FOR PREPARING SAME, LIVING RADICAL POLYMERIZATION INITIATOR, PROCESS FOR PRODUCING POLYMER WITH USE OF SAME, AND THE POLYMER
  申请人：YAMAGO Shigeru

  公开号：US20110275774A1

  公开（公告）日：2011-11-10

  An organoantimony compound represented by the formula (1), processes for producing polymers with use of the compound, and polymers wherein R 1 and R 2 are C 1 -C 8 alkyl, aryl, substituted aryl or an aromatic heterocyclic group, R 3 and R 4 are each a hydrogen atom or C 1 -C 8 alkyl, and R 5 is aryl, substituted aryl, an aromatic heterocyclic group, oxycarbonyl or cyano.

  一种有机锑化合物，其化学式表示为(1)，使用该化合物制备聚合物的方法，以及其中R1和R2为C1-C8烷基、芳基、取代芳基或芳香族杂环基，R3和R4分别为氢原子或C1-C8烷基，R5为芳基、取代芳基、芳香族杂环基、氧羰基或氰基的聚合物。
• Use Of A Combination Chain Transfer And Activating Agent To Control Molecular Weight And Optical Density Of Pd Catalyzed Norbornene Polymers
  申请人：Rhodes Larry F.

  公开号：US20110009578A1

  公开（公告）日：2011-01-13

  A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.
• WATER SOLUBLE NORBORNENE-TYPE POLYMERS AND PHOTOIMAGEABLE COMPOSITIONS THEREOF
  申请人：PROMERUS, LLC

  公开号：US20140349233A1

  公开（公告）日：2014-11-27

  Embodiments in accordance with the present invention encompass water soluble polycyclic vinyl addition polymers having a norbornene type repeat unit derived from a norbornene type of monomer that encompasses a saccharide functional moiety. Embodiments in accordance with the present invention also encompass low and high molecular weight polymers with low catalyst loading.
• US9328179B2
  申请人：——

  公开号：US9328179B2

  公开（公告）日：2016-05-03
• [EN] USE OF A COMBINATION CHAIN TRANSFER AND ACTIVATING AGENT TO CONTROL MOLECULAR WEIGHT AND OPTICAL DENSITY OF PD CATALYZED NORBORNENE POLYMERS<br/>[FR] UTILISATION D'UN AGENT COMBINÉ DE TRANSFERT DE CHAÎNE ET D'ACTIVATION POUR RÉGULER LA MASSE MOLÉCULAIRE ET LA DENSITÉ OPTIQUE DE POLYMÈRES DE NORBORNÈNE CATALYSÉ PAR PD
  申请人：PROMERUS LLC

  公开号：WO2008121804A1

  公开（公告）日：2008-10-09

  [EN] A method of controlling the molecular weight of poly(cyclic) olefin (norbornene-type) polymers and activating the polymerization thereof with a single material is provided. Such method include adding a chain transfer/activating agent to a mixture of monomer(s), catalyst, solvent and an optional cocatalyst and polymerizing the mixture to form a polymer. It is shown that the amount of chain transfer/activating agent in the mixture can serve to control the molecular weight of the resulting polymer, its percent conversion or both, and in some embodiments the optical density of the resulting polymer.
  [FR] L'invention concerne un procédé de régulation de la masse moléculaire de polymères d'oléfine (de type norbornène) poly(cycliques) et d'activation de leur polymérisation avec un matériau unique. Un tel procédé comporte l'addition d'un agent de transfert de chaîne/activation à un mélange de monomère(s), d'un catalyseur, d'un solvant et d'un cocatalyseur facultatif ainsi que la polymérisation du mélange pour former un polymère. Il est montré que la quantité d'agent de transfert de chaîne/activation dans le mélange peut servir à réguler la masse moléculaire du polymère résultant, sa conversion en pourcentage ou les deux, et dans certains modes de réalisation, la densité optique du polymère résultant.