Heptanitrocubane | 99393-62-1

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: Heptanitrocubane
• 英文别名: 1,2,3,4,5,6,7-heptanitrocubane
• CAS: 99393-62-1
• 化学式: C₈HN₇O₁₄
• 分子量: 419.134
• InChiKey: GUPWSTKEIMSQHI-UHFFFAOYSA-N

物化性质

• 沸点：
  845.8±65.0 °C(Predicted)
• 密度：
  2.71±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -3
• 重原子数：
  29
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  321
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  Heptanitrocubane 在 lithium hexamethyldisilazane 、 亚硝酰氯 、 臭氧 作用下， 以 二氯甲烷 为溶剂， 以55%的产率得到Octanitrocubane
  参考文献：
  名称：

  Hepta- and Octanitrocubanes

  摘要：

  Four of the eight nitro groups of octanitrocubane 1 are introduced by functional group modification, three more by the astonishingly rapid, low-temperature N(2)O(4) nitration of sequentially formed polynitrocubyl anions, and the eighth and last by nitrosation of the heptanitrocubyl anion followed by ozonation.

  DOI：

  10.1002/(sici)1521-3773(20000117)39:2<401::aid-anie401>3.0.co;2-p
• 作为产物：
  描述：

  1,3,5,7-Tetranitrocubane 在 sodium hexamethyldisilazane 、 dinitrogen tetraoxide 作用下， 以 四氢呋喃 、 2-甲基丁烷 为溶剂， 以74%的产率得到Heptanitrocubane
  参考文献：
  名称：

  Hepta- and Octanitrocubanes

  摘要：

  Four of the eight nitro groups of octanitrocubane 1 are introduced by functional group modification, three more by the astonishingly rapid, low-temperature N(2)O(4) nitration of sequentially formed polynitrocubyl anions, and the eighth and last by nitrosation of the heptanitrocubyl anion followed by ozonation.

  DOI：

  10.1002/(sici)1521-3773(20000117)39:2<401::aid-anie401>3.0.co;2-p

文献信息

• ENERGETIC COCRYSTALS FOR TREATMENT OF A SUBTERRANEAN FORMATION
  申请人：HALLIBURTON ENERGY SERVICES, INC.

  公开号：US20160177698A1

  公开（公告）日：2016-06-23

  The present invention relates to energetic cocrystals, and to methods for using the same for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation, the method including obtaining or providing a composition including energetic cocrystals. Each energetic cocrystal independently includes an energetic compound and a secondary material. The method also includes placing the composition in a subterranean formation.

  本发明涉及具有能量共晶体的相关技术，以及使用这些技术治疗地下地层的方法。在各种实施例中，本发明提供了一种治疗地下地层的方法，该方法包括获得或提供包括能量共晶体的组合物。每个能量共晶体独立地包括一个能量化合物和一个辅助材料。该方法还包括将该组合物放置在地下地层中。
• Concealed amalgamated explosive neutralizer and method of manufacture
  申请人：I P Creations Limited

  公开号：US10288390B2

  公开（公告）日：2019-05-14

  A concealed amalgamated neutralizer covertly combines neutralizer material comprised of various combinations of inert materials such as calcium carbonate or silicates with common explosive material for the prevention of malicious use of the explosive material in improvised explosive devices. The concealed amalgamated neutralizer device may vary in shape, size, and color and is therefore adaptable to varying methods of containment typified by common pyrotechnic products. The neutralizer material mimics the explosive material of the pyrotechnic products without detection. Upon disassembly of a concealed amalgamated neutralizer device, the neutralizer material is mixed with and neutralizes the explosive material rendering the explosive material useless as a component for an improvised explosive device.

  隐蔽式混和中和器隐蔽地将由碳酸钙或硅酸盐等惰性材料的各种组合构成的中和 材料与普通爆炸材料结合在一起，以防止在简易爆炸装置中恶意使用爆炸材料。隐蔽式汞齐化中和剂装置的形状、大小和颜色各不相同，因此可适用于普通烟火产品的各种封闭方法。中和剂材料模仿烟火产品的爆炸材料，不会被发现。在拆卸隐蔽式混合中和剂装置时，中和剂材料与爆炸材料混合并中和，使爆炸材料成为简易爆炸装置的无用部件。
• Energetic cocrystals for treatment of a subterranean formation
  申请人：Halliburton Energy Services, Inc.

  公开号：US10309212B2

  公开（公告）日：2019-06-04

  The present invention relates to energetic cocrystals, and to methods for using the same for treatment of a subterranean formation. In various embodiments, the present invention provides a method of treating a subterranean formation, the method including obtaining or providing a composition including energetic cocrystals. Each energetic cocrystal independently includes an energetic compound and a secondary material. The method also includes placing the composition in a subterranean formation.

  本发明涉及高能茧晶以及使用高能茧晶处理地下地层的方法。在各种实施方案中，本发明提供了一种处理地下地层的方法，该方法包括获得或提供一种包括高能椰晶的组合物。每种高能椰晶都独立地包括一种高能化合物和一种辅助材料。该方法还包括将组合物置于地下岩层中。
• Agriculture system and method
  申请人：Oliver Troy

  公开号：US10542660B2

  公开（公告）日：2020-01-28

  An agricultural enhancement method for removing or overcoming soil fragipan, hardpan, or other natural and/or artificial soil compaction barriers is disclosed. These barriers prevent root and/or water penetration, which inhibits agricultural development. Consequently, removing and overcoming these barriers is beneficial to the soil and to agricultural yields.

  本发明公开了一种农业改良方法，用于消除或克服土壤脆片、硬板或其他天然和/或人工土壤压实障碍。这些障碍阻碍了根系和/或水分的渗透，从而抑制了农业的发展。因此，消除和克服这些障碍有利于土壤和农业产量。
• Power generation systems and methods regarding same
  申请人：Brilliant Light Power, Inc.

  公开号：US10753275B2

  公开（公告）日：2020-08-25

  A solid fuel power source that provides at least one of thermal and electrical power such as direct electricity or thermal to electricity is further provided that powers a power system comprising (i) at least one reaction cell for the catalysis of atomic hydrogen to form hydrinos, (ii) a chemical fuel mixture comprising at least two components chosen from: a source of H2O catalyst or H2O catalyst; a source of atomic hydrogen or atomic hydrogen; reactants to form the source of H2O catalyst or H2O catalyst and a source of atomic hydrogen or atomic hydrogen; one or more reactants to initiate the catalysis of atomic hydrogen; and a material to cause the solid fuel to be highly conductive, (iii) at least one set of electrodes that confine the fuel and an electrical power source that provides a short burst of low-voltage, high-current electrical energy to initiate rapid kinetics of the hydrino reaction and an energy gain due to forming hydrinos, (iv) a product recovery systems such as a condenser (v) a reloading system, (vi) at least one of hydration, thermal, chemical, and electrochemical systems to regenerate the fuel from the reaction products, (vii) a heat sink that accepts the heat from the power-producing reactions, (viii) a power conversion system that may comprise a direct plasma to electric converter such as a plasmadynamic converter, magnetohydrodynamic converter, electromagnetic direct (crossed field or drift) converter, direct converter, and charge drift converter or a thermal to electric power converter such as a Rankine or Brayton-type power plant.

  进一步提供了一种固体燃料动力源，可提供热能和电能中的至少一种，如直接电能或热能转化为电能，其动力系统包括(i)至少一个用于催化原子氢以形成水合氢的反应池，(ii)一种化学燃料混合物，包括至少两种选自以下的组分H2O 催化剂或 H2O 催化剂源； 原子氢或原子氢源； 形成 H2O 催化剂或 H2O 催化剂源和原子氢或原子氢源的反应物； 启动原子氢催化的一种或多种反应物；(iii)至少一组限制燃料的电极和一个提供短时低压大电流电能的电源，以启动水合反应的快速动力学和由于形成水合氢而产生的能量增益；(iv)一个产品回收系统，如冷凝器；(v)一个重新装载系统；(vi)水合、热、化学和电化学系统中的至少一个，以再生燃料；(viii)至少一组限制燃料的电极和一个提供短时低压大电流电能的电源，以启动水合反应的快速动力学和由于形成水合氢而产生的能量增益、(viii) 动力转换系统，可包括等离子体直接转换为电能的转换器，如等离子体动力转换器、磁流体动力转换器、电磁直接（交叉场或漂移）转换器、直接转换器和电荷漂移转换器，或热能转换为电能的转换器，如朗肯或布雷顿式发电厂。