iron(III) isopropoxide | 14995-22-3

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机铁
• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: iron(III) isopropoxide
• 英文别名: Iron(3+);propan-2-olate
• CAS: 14995-22-3
• 化学式: C₉H₂₁FeO₃
• 分子量: 233.111
• InChiKey: QUHDSMAREWXWFM-UHFFFAOYSA-N

物化性质

• 沸点：
  82℃
• 密度：
  0.79
• 闪点：
  12°(54°F)
• 稳定性/保质期：
  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  3.24
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  69.2
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• TSCA：
  Yes
• 危险等级：
  4.1
• 包装等级：
  III
• 危险类别：
  4.1

SDS

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Section 1: Product Identification
Chemical Name: Iron (III) i-propoxide (99.9+%-Fe)
CAS Registry Number: 14995-22-3
Formula: Fe(OC3H7)3
EINECS Number: None
Chemical Family: metal alkoxide
Synonym: Ferric propoxide, Iron propylate

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 14995-22-3 100% 1 mg/m3 (Sol Fe) no data

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Section 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Ingestion, skin, inhalation, eyes
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes irritation, redness, and pain to skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No information on the physiological effects of ingestion.
Acute Health Affects: Irritating to skin, eyes and respiratory tract.
Prolonged ingestion may lead to damage to the liver and pancreas. Prolonged inhalation of dusts may cause
Chronic Health Affects:
pulmonary fibrosis.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: 53°F(2-propanol)
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, water, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Contact with moisture will produce flammable isopropanol

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SECTION 6: Accidental Release Measures
Remove sources of ignition. Small spills can be mixed with vermiculite, sodium carbonate or other suitable non
Spill and Leak Procedures:
combustible adsorbent and swept up.

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SECTION 7: Handling and Storage
Keep material in a tightly sealed container in a cool dry place. Prolonged exposure to the moist air will result in
Handling and Storage:
degradation of the product. Handle and store material under a dry atmosphere.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: brown to black solid
Molecular Weight: 233.12
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: slight alcohol odor
Solubility in Water: hydrolyzes in water

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SECTION 10: Stability and Reactivity
Stability: moisture sensitive
Hazardous Polymerization: no hazardous polymerization
Prolonged contact with air or moisture. Keep away from heat and ignition sources including open flame and
Conditions to Avoid:
electrostatic discharge.
Incompatibility: Oxidizing agents, halogens and active metals
Decomposition Products: carbon dioxide, carbon monoxide, organic fumes, and iron oxide

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data
Mutagenic Effects: No data
Tetratogenic Effects: No data

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

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SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: None

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  iron(III) isopropoxide 、 cobalt(2+);(Z)-4-oxopent-2-en-2-olate;(E)-4-oxopent-2-en-2-olate 生成 cobalt;iron;diperoxide
  参考文献：
  名称：

  NANAO, TSUTOMU;EGUCHI, TAMIYUKI

  摘要：

  DOI：
• 作为产物：
  描述：

  sodium isopropylate 、 三氯化铁 生成 iron(III) isopropoxide
  参考文献：
  名称：

  TUROVA, N. YA.;ROGOVA, T. V.;KUCHEJKO, S. I.;TUREVSKAYA, E. N.

  摘要：

  DOI：

文献信息

• Synthesis, structure and magnetic properties of multipod-shaped cobalt ferrite nanocrystals
  作者：Mohammed Hennous、E. Venkata Ramana、David M. Tobaldi、Benilde F. O. Costa、M. A. Valente、Joao Labrincha、Mohamed Karmaoui

  DOI：10.1039/c9nj02237f

  日期：——

  nanocrystals were characterized by X-ray diffraction, high-resolution transmission electron microscopy, Raman spectroscopy, magnetometry and Mössbauer spectroscopy, to understand their structure and magnetic properties. These CoFe2O4 nanoparticles have the smallest particle size reported ever, with a mean diameter of ∼3 nm. The coercivity was found to be larger compared to that reported in the literature

  我们应用一般的非水途径形成单，双，三，四，六足和多足尖晶石磁性铁氧体金属氧化物（CoFe 2 O 4）纳米晶体。通过X射线衍射，高分辨率透射电子显微镜，拉曼光谱，磁力法和Mössbauer光谱对CoFe 2 O 4磁性纳米晶体进行了表征，以了解其结构和磁性。这些CoFe 2 O 4纳米粒子的粒径是有史以来最小的，平均直径约为3纳米。发现矫顽力比文献中球形颗粒的矫顽力大。Mössbauer光谱表明在室温以上会发生磁转变，其中20％的Fe离子会转变为顺磁性状态（约400 K）。根据磁性参数的热依赖性，估计阻断温度约为425K。这些研究表明我们的CoFe 2 O 4纳米晶体不同于它们的立方/球形晶体，它们通常显示出单畴特征。这些CoFe 2 O 4纳米晶体显示出强的形状各向异性依赖性的磁性。
• TUROVA, N. YA.;ROGOVA, T. V.;KUCHEJKO, S. I.;TUREVSKAYA, E. N.
  作者：TUROVA, N. YA.、ROGOVA, T. V.、KUCHEJKO, S. I.、TUREVSKAYA, E. N.

  DOI：——

  日期：——
• NANAO, TSUTOMU;EGUCHI, TAMIYUKI
  作者：NANAO, TSUTOMU、EGUCHI, TAMIYUKI

  DOI：——

  日期：——