钠2-乙基-1-己醇 | 38411-13-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 钠2-乙基-1-己醇
• 英文名称: Sodium 2-ethylhexanolate
• 英文别名: sodium;2-ethylhexan-1-olate
• CAS: 38411-13-1
• 化学式: C8H17NaO
• 分子量: 152.21
• InChiKey: BFDXQZBRSCAZOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.43
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-Chloroallyl (5R,6S)-6-(1(R)-hydroxyethyl)-2-<(1(R)-oxo-3(S)-thiolanyl)thio>-2-penem-3-carboxylate 、 三苯基膦 、 四(三苯基膦)钯 、 钠2-乙基-1-己醇 生成 Sodium 5R,6S-6-(1R-Hydroxyethyl)-2-(1R-oxo-3S-thiolanylthio)-2-penem-3-carboxylate
  参考文献：
  名称：

  VOLKMANN, ROBERT A.

  摘要：

  DOI：
• 作为产物：
  描述：

  2-乙基己醇 生成 钠2-乙基-1-己醇
  参考文献：
  名称：

  STRECK, ROLAND;MAIER, HANS-DIETER

  摘要：

  DOI：

文献信息

• Functionalized rubbery polymers
  申请人：THE GOODYEAR TIRE & RUBBER COMPANY

  公开号：EP1792892A2

  公开（公告）日：2007-06-06

  This invention discloses a functional monomer, its use in a polymer, a rubbery composition, a tire, and a process to make such a rubbery composition. The functional monomer has a structural formula selected from the group consisting of: wherein the R1 groups can be the same or different and represent hydrogen atoms or alkyl groups containing from 1 to 8 carbon atoms, wherein R2 represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms, wherein R3 represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms, wherein R4 represents a hydrogen atom or an alkyl group containing from 1 to 8 carbon atoms, with the proviso that if R3 represents an alkyl group then R4 represents a hydrogen atom, and with the proviso that R4 represents an alkyl group then R3 represents a hydrogen atom, and wherein the R5 groups can be the same or different and represent alkyl groups containing from 1 to 8 carbon atoms.

  本发明揭示了一种功能单体，其在聚合物中的使用，橡胶组合物，轮胎以及制造这种橡胶组合物的过程。该功能单体具有以下结构式中所选的结构式：其中R1基团可以相同或不同，并表示氢原子或含有1至8个碳原子的烷基基团，其中R2表示氢原子或含有1至8个碳原子的烷基基团，其中R3表示氢原子或含有1至8个碳原子的烷基基团，其中R4表示氢原子或含有1至8个碳原子的烷基基团，但如果R3表示烷基基团，则R4表示氢原子，如果R4表示烷基基团，则R3表示氢原子，其中R5基团可以相同或不同，并表示含有1至8个碳原子的烷基基团。
• FUNCTIONALIZED MONOMERS FOR SYNTHESIS OF RUBBERY POLYMERS
  申请人：Halasa Farhan Adel

  公开号：US20050131181A1

  公开（公告）日：2005-06-16

  This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of wherein R and R′ can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula wherein R and R′ can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.

  本发明揭示了一种合成胺官能化单体的过程，其中包括（1）将二级胺与2,3-二卤代丙烯反应，以产生含有乙烯卤代基的二级胺，其结构式选自以下组中的一种：其中R和R'可以相同或不同，代表含有1至约10个碳原子的烯丙基，烷氧基或烷基基团，X代表卤素原子，m代表4至约10的整数，X代表卤素原子；以及（2）将含有乙烯卤代基的二级胺与乙烯基镁卤反应，以产生具有结构式的单体：其中R和R'可以相同或不同，代表含有1至约10个碳原子的烷基，烯丙基或烷氧基基团，m代表约4至约10的整数。
• Functionalized monomers for synthesis of rubbery polymers
  申请人：The Goodyear Tire & Rubber Company

  公开号：US20040122194A1

  公开（公告）日：2004-06-24

  This invention discloses a process for synthesizing an amine functionalized monomer that comprises (1) reacting a secondary amine with a 2,3-dihalopropene to produce a vinyl halide containing secondary amine having a structural formula selected from the group consisting of 1 wherein R and R′ can be the same or different and represent allyl, alkoxyl or alkyl groups containing from 1 to about 10 carbon atoms, and wherein X represents a halogen atom, and wherein m represents an integer from 4 to about 10, and wherein X represents a halogen atom; and (2) reacting the vinyl halide containing secondary amine with a vinyl magnesium halide to produce the monomer having a structural formula 2 wherein R and R′ can be the same or different and represent alkyl, allyl or alkoxyl groups containing from 1 to about 10 carbon atoms, and wherein m represents an integer from about 4 to about 10.

  本发明揭示了一种合成胺基单体的过程，包括(1)将二级胺与2,3-二卤代丙烯反应，产生含有乙烯卤代的二级胺，其结构式选自以下组合中的一种：其中R和R'可以相同或不同，代表含有1至约10个碳原子的丙烯基、烷氧基或烷基，X代表卤素原子，m代表从4至约10的整数，X代表卤素原子；(2)将含有乙烯卤代的二级胺与乙烯基镁卤反应，产生具有结构式2的单体，其中R和R'可以相同或不同，代表含有1至约10个碳原子的烷基、丙烯基或烷氧基，m代表从约4至约10的整数。
• Process for producing a thermoplastic polymer containing segments of a diamide
  申请人：DSM IP ASSETS B.V.

  公开号：US10040904B2

  公开（公告）日：2018-08-07

  Process for the production of a thermoplastic polymer comprising segments of a diamide, the process comprising: 1) a first step of preparing a reaction mixture comprising a diamine H2N—Y—NH2 Form. (I), and a diester of a dicarboxylic acid Form. (II) 2) a second step of heating the reaction mixture to a temperature at least 5° C. above the crystallization temperature of the diester and a least 5° C. below the melting temperature of the formed amide (formula III) in the presence of an alkaline or earth alkaline alkoxy catalyst Form. (III) wherein X and Y are the same or different and are an aliphatic group comprising 2-12 carbon atoms or an aromatic group comprising 6-20 carbon atoms, R1 and R2 are the same or different and are an aliphatic group comprising 2-15 carbon atoms and wherein R equals R1 or R2 and are the same or different. 3) optionally a third step of quenching the catalyst of the reaction mixture obtained in the second step by adding an acid to the reaction mixture and 4) a fourth step of adding further components to the reaction mixture obtained in the second step, or if the third step has been applied to the reaction mixture obtained in the third step, and so producing the thermoplastic polymer comprising the segments of the diamide.

  由二元胺段组成的热塑性聚合物的生产工艺，该工艺包括1) 第一步制备反应混合物，该混合物包括二胺 H2N-Y-NH2 形式。(I) 和二羧酸二酯的反应混合物。(II) 2) 第二步，在碱性或土碱性烷氧基催化剂存在下，将反应混合物加热至高于二酯结晶温度至少 5 摄氏度、低于所形成的酰胺（式 III）的熔化温度至少 5 摄氏度的温度。(III)其中X和Y相同或不同并且是由2-12个碳原子组成的脂肪族基团或由6-20个碳原子组成的芳香族基团，R1和R2相同或不同并且是由2-15个碳原子组成的脂肪族基团，其中R等于R1或R2并且相同或不同。3）可选的第三步，通过向反应混合物中加入酸来淬灭第二步中得到的反应混合物的催化剂；4）第四步，向第二步中得到的反应混合物中加入更多的组分，或者如果第三步已经应用于第三步中得到的反应混合物，从而生产出包含二酰胺段的热塑性聚合物。
• Process for preparing mixtures of epoxidized fatty acid esters
  申请人：PROVIRON HOLDING N.V.

  公开号：US10858611B2

  公开（公告）日：2020-12-08

  The present invention relates to a process for preparing two mixtures of epoxidized fatty acid esters, comprising in the order given a transesterification of an epoxidized vegetable oil, followed by a reduction of the volatile saturated non-epoxidized fraction by short path distillation of the transesterified epoxidized vegetable oil, followed by a selection on the one hand of the non-vaporized fraction (residue) of the previous process step as the first mixture of epoxidized fatty acid esters and a selection on the other hand of the vaporized fraction (distillate) as the second mixture of epoxidized fatty acid esters. The first mixture is in particular suitable as plasticizer in halogenated polymers, the second mixture being particularly suitable as plasticizer in non-halogenated polymers.

  本发明涉及一种制备两种环氧化脂肪酸酯混合物的工艺，按照给定的顺序包括对环氧化植物油进行酯交换反应，然后通过对酯交换反应后的环氧化植物油进行短程蒸馏，减少挥发性饱和非氧化馏分、然后一方面选择前一工艺步骤中的非汽化馏分（残渣）作为环氧化脂肪酸酯的第一混合物，另一方面选择汽化馏分（蒸馏物）作为环氧化脂肪酸酯的第二混合物。第一种混合物特别适合用作卤化聚合物的增塑剂，第二种混合物特别适合用作非卤化聚合物的增塑剂。