Dehydrocamphen | 6703-36-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: Dehydrocamphen
• 英文别名: camphene；5,5-dimethyl-6-methylene-norborn-2-ene；5,5-Dimethyl-6-methylen-norborn-2-en；Camphenen；Isocamphodiene；5,5-dimethyl-6-methylidenebicyclo[2.2.1]hept-2-ene
• CAS: 6703-36-2
• 化学式: C₁₀H₁₄
• 分子量: 134.221
• InChiKey: UANSRJDUSZXSBW-UHFFFAOYSA-N

物化性质

• 熔点：
  41.5-42 °C
• 沸点：
  149-150 °C(Press: 763 Torr)
• 密度：
  0.8711 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Dehydrocamphen 在 碘 作用下， 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  UV-spectroscopic study of complex formation by certain cycloolefins with tetracyanoethylene and molecular iodine

  摘要：

  UV spectroscopy of charge-transfer complexes (CTCs) with tetracyanoethylene (TCE) and iodine has been used to study the relative donor ability of mono- and bicycloolefins and the stability of the CTCs. The donor ability of bicycloolefins, characterized by v(CT)(TCE), increases with increase in ring strain. The equilibrium constants for complex formation of bicycloolefins with TCE are linearly related to the rate constants of the reaction of epoxidation by tert-butyl hydroperoxide.

  DOI：

  10.1007/bf00962380
• 作为产物：
  描述：

  2,3,3-Trimethylbicyclo<2.2.1>hept-5-en-2-ol 在 吡啶 、 三氯氧磷 作用下， 反应 20.0h， 生成 Dehydrocamphen
  参考文献：
  名称：

  Synthesen in der Isocamphanreihe, 39. Mitt.: Verbesserung derDiels-Alder-Reaktion von Cyclopentadien mit Mesityloxid durch Ultraschall und eine neue Synthese von Dehydrocamphen

  摘要：

  The synthesis of the valuable terpenic synthon 2-acetyl-3,3-dimethylbicyclo[2.2.1]hept-5-tene is clearly improved concerning the yield and especially the reaction time by applying ultrasound on the Diels-Alder reaction of cyclopentadiene with mesityl oxide. A new synthesis of dehydrocamphene and its odour impression is described.

  DOI：

  10.1007/bf00812706

文献信息

• Nametkin; Zabrodina, Chemische Berichte, 1928, vol. 61, p. 1493
  作者：Nametkin、Zabrodina

  DOI：——

  日期：——
• Synthesen in der Isocamphanreihe, 39. Mitt.: Verbesserung derDiels-Alder-Reaktion von Cyclopentadien mit Mesityloxid durch Ultraschall und eine neue Synthese von Dehydrocamphen
  作者：G. Buchbauer、H. Spreitzer、I. Bauer、H. Knobel

  DOI：10.1007/bf00812706

  日期：——

  The synthesis of the valuable terpenic synthon 2-acetyl-3,3-dimethylbicyclo[2.2.1]hept-5-tene is clearly improved concerning the yield and especially the reaction time by applying ultrasound on the Diels-Alder reaction of cyclopentadiene with mesityl oxide. A new synthesis of dehydrocamphene and its odour impression is described.
• UV-spectroscopic study of complex formation by certain cycloolefins with tetracyanoethylene and molecular iodine
  作者：G. V. Belysheva、A. N. Egorochkin、P. G. Sennikov、M. A. Lopatin、V. V. Voronenkov

  DOI：10.1007/bf00962380

  日期：1990.6

  UV spectroscopy of charge-transfer complexes (CTCs) with tetracyanoethylene (TCE) and iodine has been used to study the relative donor ability of mono- and bicycloolefins and the stability of the CTCs. The donor ability of bicycloolefins, characterized by v(CT)(TCE), increases with increase in ring strain. The equilibrium constants for complex formation of bicycloolefins with TCE are linearly related to the rate constants of the reaction of epoxidation by tert-butyl hydroperoxide.