N,N'-bis[3-(triethoxysilyl)propyl]perylene-3,4,9,10-tetracarboxylic diimide | 262360-40-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: N,N'-bis[3-(triethoxysilyl)propyl]perylene-3,4,9,10-tetracarboxylic diimide
• 英文别名: 7,18-Bis(3-triethoxysilylpropyl)-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene-6,8,17,19-tetrone
• CAS: 262360-40-7
• 化学式: C₄₂H₅₀N₂O₁₀Si₂
• 分子量: 799.037
• InChiKey: YQSWWUHRUMLGCG-UHFFFAOYSA-N

物化性质

• 沸点：
  804.1±55.0 °C(Predicted)
• 密度：
  1.251±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.81
• 重原子数：
  56
• 可旋转键数：
  20
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  130
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  3-氨基丙基三乙氧基硅烷 以 N-甲基吡咯烷酮 、 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 10.0h， 生成 N,N'-bis[3-(triethoxysilyl)propyl]perylene-3,4,9,10-tetracarboxylic diimide
  参考文献：
  名称：

  イミド化合物の製造方法

  摘要：

  提供一种能够比传统方法更容易去除副产物，并且以低成本制造酰亚胺化合物的方法。从胺化合物制备酰亚胺化合物的方法，该制备方法包括以下步骤：第一步骤是将酮化合物与下式（1）中表示的胺化合物（式中，R表示一价有机基）反应；R-NH2（1）；第二步骤是将所得化合物与羧酸无水物反应。

  公开号：

  JP2015107944A

文献信息

• A luminescent steroid-based organogel: ON–OFF photoswitching by dopant interplay and templated synthesis of fluorescent nanoparticles
  作者：Valeria C. Edelsztein、Elizabeth A. Jares-Erijman、Klaus Müllen、Pablo H. Di Chenna、Carla C. Spagnuolo

  DOI：10.1039/c2jm34891h

  日期：——

  The modulation of the fluorescence emission of a perylene dye between ON and OFF states was achieved with high efficiency by means of a diarylethene photochromic compound in an organogel medium. Fluorescent gels were prepared from a steroidal low molecular weight organogelator doped with the perylene fluorophore. The compatibility of the photochromic compound in this medium and the non-destructive readout capability were demonstrated. The dye doped organogel was further used as a template and an innovative method was employed to grow fluorescent silica spherical nanoparticles with physically and chemically admixed perylene dye.

  通过在有机胶体介质中使用二芳基乙烯光致变色化合物，实现了苝染料在开关状态之间的荧光发射调制，效率极高。荧光胶体是由掺杂苝荧光分子的类固醇低分子量有机胶体形成的。证明了光致变色化合物在该介质中的兼容性和非破坏性读取能力。掺染染料的有机胶体进一步作为模板，采用创新方法生长了物理和化学混合的荧光二氧化硅球形纳米颗粒。
• Preparation of n-type semiconducting polymer nanoarrays by covalent synthesis followed by crystallization
  作者：Begum Fouzia、John Ferguson、Kelly McKenna、Louis E. McNamara、Nathan I. Hammer、Hemali Rathnayake

  DOI：10.1039/c4nj00968a

  日期：——

  electrical characterization of thin films made from polymer nanoarrays shows typical semiconducting behaviour with the electrical conductivity of 0.48 × 10−3 S cm−1. The covalent synthesis followed by solution-based crystallization of PDIB-SSQ reported herein provides a new synthesis path to make ordered-crystalline semiconducting polymer nanoarrays and ultimately a benefit for better understanding of their

  原位共价合成，然后对由per二酰亚胺桥接的倍半硅氧烷（PDIB-SSQ）衍生的n型半导体聚合物进行溶液结晶，生成了40–100 nm宽，80μm长的一维纳米阵列。通过SEM，荧光光学显微镜，SAXS，元素分析，MALDI-TOF-MS以及吸收和荧光光谱对由不同碱浓度产生的纳米结构的形貌和尺寸进行了表征。正如SAXS所揭示的那样，纳米结构由晶胞组成，晶胞参数为d [001] = 24.8Å和d [100]= 10.3，π-π的多个堆积距离范围为4.71至2.57Å。界面排列的PDI核之间的π–π相互作用有利于聚合物纳米阵列中的有序排列，从而导致聚合物阵列与d紧密堆积-间距范围从3.67到3.24Å。溶液中的纳米阵列的光谱痕迹与单体的相似，除了与聚合形式的聚合物链的π-π堆积相关的发射光谱的轻微红移特征。薄膜发射光谱遵循相似的光谱模式，并具有明显的肩峰，对应于界面π-π相互作用。聚集的聚合物纳
• Process for making electronically active functionalized silsequioxane nanostructures of controlled morphology through covalent synthesis
  申请人：Rathnayake Hemali

  公开号：US09318716B1

  公开（公告）日：2016-04-19

  Disclosed is a composition comprising perylenediimide bridged dimethylethoxysilane. Disclosed also is an electronically active nanostructure comprising perylenediimide bridged dimethylethoxysilane. Disclosed also is a process for fabricating a photovoltaic device comprising depositing an electronically active nanostructure, the nanostructure made by hydrolysis and condensation of perylenediimide bridged dimethylethoxysilane, onto a substrate.

  揭示了一种包含苝二酰亚胺桥联二甲基乙氧基硅烷的组合物。还揭示了一种电子活性纳米结构，其中包含苝二酰亚胺桥联二甲基乙氧基硅烷。还揭示了一种制造光伏器件的工艺，包括将电子活性纳米结构沉积在基底上，该纳米结构由苝二酰亚胺桥联二甲基乙氧基硅烷的水解和缩合制成。
• Synthesis of Silica Encapsulated Perylenetetracarboxylic Diimide Core–Shell Nanoellipsoids
  作者：Hailin Wang、Karola Schaefer、Andrij Pich、Martin Moeller

  DOI：10.1021/cm2017328

  日期：2011.11.8

  Silica encapsulated perylenediimide (PDI) nanoellipsoids with core-shell structure have been synthesized in solution by a combination of precipitation method and sol-gel chemistry. Electron energy loss spectrum (EELS) analysis proves that the obtained composite particles consist of a PDI core and a silica shell. The UV-vis and fluorescence spectra show the strong pi-pi stacking state of PDI molecules in the composite colloids. The silica deposition process on the PDI surface can be well controlled allowing variation of the shell thickness from 10 to 50 nm. Thermogravimetrical analysis data indicate that the thermal stability of PDI increases after deposition of a silica shell. The photostability of PDI is enhanced by the introduction of silica shell. The silica coating improves the dispersibility of PDI in different solvents and in polymer films.