(-)-myrtenol | 36203-26-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (-)-myrtenol
• 英文别名: [(1R,5S)-6,6-dimethyl-3-bicyclo[3.1.1]hept-2-enyl]methanol
• CAS: 36203-26-6
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: YKYRCPFRUXTGHV-DTWKUNHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (-)-myrtenol 在 4-二甲氨基吡啶 、 三乙胺 、 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 生成 myrtenol β-phenylpropionate
  参考文献：
  名称：

  Appendino, Giovanni; Cravotto, Giancarlo; Gariboldi, Pierluigi, Gazzetta Chimica Italiana, 1994, vol. 124, # 1, p. 1 - 4

  摘要：

  DOI：

文献信息

• Oxidation of Alcohols in Continuous Flow with a Solid Phase Hypervalent Iodine Catalyst
  作者：Kathrin Bensberg、Athanasios Savvidis、Frederic Ballaschk、Adrián Gómez‐Suárez、Stefan F. Kirsch

  DOI：10.1002/chem.202304011

  日期：2024.4.5

  Discover a sustainable, solid-phase catalyst for fast and efficient oxidation of a wide range of alcohols to their corresponding carbonyls in continuous flow! The new approach enables successful oxidation of various alcohols, including previously unreactive primary alcohols, with minimal catalyst loadings and rapid product accessibility.

  发现一种可持续的固相催化剂，用于在连续流动中快速有效地将各种醇氧化为其相应的羰基化合物！新方法能够成功氧化各种醇，包括以前不反应的伯醇，并具有最小的催化剂负载量和快速的产品可获取性。
• A Convenient One-Step Synthesis of Glycidyl Ethers
  作者：Gilbert Mouzin、Henri Cousse、Jean-Pierre Rieu、Alain Duflos

  DOI：10.1055/s-1983-30243

  日期：——
• Separation of amino acid enantiomers using supported liquid membrane extraction with chiral phosphates and phosphonates
  作者：Paweŀ Dźygiel、Piotr Wieczorek、JanA˚ke Jonsson、Malgorzata Milewska、Pawel Kafarski

  DOI：10.1016/s0040-4020(99)00531-1

  日期：1999.8

  A series of dialkyl and monoalkyl phosphates, phosphites and phosphinates based on (-)-menthol and (-)-nopol were synthesized and used as carriers for transport of aromatic amino acids through supported liquid membranes. Although all the compounds were found to be effective carriers (with transport rate dependent on their structure) the enantioselectivity of the process obtained was low or moderate. (C) 1999 Elsevier Science Ltd. All rights reserved.
• Appendino, Giovanni; Cravotto, Giancarlo; Gariboldi, Pierluigi, Gazzetta Chimica Italiana, 1994, vol. 124, # 1, p. 1 - 4
  作者：Appendino, Giovanni、Cravotto, Giancarlo、Gariboldi, Pierluigi、Gabetta, Bruno、Bombardelli, Ezio

  DOI：——

  日期：——