calcium(II) 8-quinolinolate | 220454-75-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: calcium(II) 8-quinolinolate
• 英文别名: Calcium;quinolin-8-olate；calcium;quinolin-8-olate
• CAS: 220454-75-1
• 化学式: C₁₈H₁₂CaN₂O₂
• 分子量: 328.383
• InChiKey: SSRDUXKBRJYDLX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.24
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tris(quinolin-8-olato)europium(III) 、 calcium(II) 8-quinolinolate 在 1,2,4,5-tetramethylbenzene 作用下， 以 neat (no solvent) 为溶剂， 以15%的产率得到
  参考文献：
  名称：

  Novel rare earth quinolinolate complexes

  摘要：

  The reaction of curopium 8-quinolinolate Eu(OQ)(3) with calcium 8-quinolinolate, Ca(OQ)(2), in the flux 1,2,4,5-tetramethylbenzene (TMB) at 210 degrees C yields thebimetallic [Eu2Ca(OQ)(8)], which is a linear tri-nuclear complex with two eight coordinate europium atoms flanking a six coordinate calcium atom bonded by six bridging phenolate oxygen atoms. A similar reaction between La(OQ)(3) and CO(OQ)(2) gave [LaCO2(OQ)(7)], in which two six coordinate cobalt atoms flank an eight coordinate lanthanum atom with six bridging phenolate oxygen atoms and a terminal OQ group. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2007.04.253

文献信息

• TRANSLUCENT SUBSTRATE, ORGANIC LED ELEMENT AND METHOD OF MANUFACTURING TRANSLUCENT SUBSTRATE
  申请人：AGC Inc.

  公开号：EP2995595B1

  公开（公告）日：2020-11-25
• Novel rare earth quinolinolate complexes
  作者：Glen B. Deacon、Craig M. Forsyth、Peter C. Junk、Ulrich Kynast、Gerd Meyer、Joanne Moore、Jennyfer Sierau、Aron Urbatsch

  DOI：10.1016/j.jallcom.2007.04.253

  日期：2008.2

  The reaction of curopium 8-quinolinolate Eu(OQ)(3) with calcium 8-quinolinolate, Ca(OQ)(2), in the flux 1,2,4,5-tetramethylbenzene (TMB) at 210 degrees C yields thebimetallic [Eu2Ca(OQ)(8)], which is a linear tri-nuclear complex with two eight coordinate europium atoms flanking a six coordinate calcium atom bonded by six bridging phenolate oxygen atoms. A similar reaction between La(OQ)(3) and CO(OQ)(2) gave [LaCO2(OQ)(7)], in which two six coordinate cobalt atoms flank an eight coordinate lanthanum atom with six bridging phenolate oxygen atoms and a terminal OQ group. (C) 2007 Elsevier B.V. All rights reserved.