3-Ethyl-7,7-dimethoxy-1-methyl-4-phenyl-cyclohepta-1,3,5-triene | 143768-75-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-Ethyl-7,7-dimethoxy-1-methyl-4-phenyl-cyclohepta-1,3,5-triene
• 英文别名: 3-Ethyl-7,7-dimethoxy-1-methyl-4-phenylcyclohepta-1,3,5-triene
• CAS: 143768-75-6
• 化学式: C₁₈H₂₂O₂
• 分子量: 270.371
• InChiKey: KJFKSRYOABHMBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-Ethyl-7,7-dimethoxy-1-methyl-4-phenyl-cyclohepta-1,3,5-triene 在 硫酸 作用下， 生成 4-Ethyl-2-methyl-5-phenyl-cyclohepta-2,4,6-trienone
  参考文献：
  名称：

  Regioselective synthesis of substituted tropones and azulenes using anodic oxidation of cycloheptatriene systems as the key reaction

  摘要：

  Regioselective synthesis of di- and trisubstituted tropones has been attained by utilizing anodic oxidation of cycloheptatriene systems as the key reaction. This anodic oxidation has also been found to be useful for the regioselective synthesis of mono- and disubstituted azulenes.

  DOI：

  10.1016/s0040-4039(00)74254-7
• 作为产物：
  描述：

  1-phenyl-3-methoxy-7-ethylcycloheptatriene 在 正丁基锂 、 sodium methylate 、 四乙基对甲苯磺酸铵 作用下， 生成 3-Ethyl-7,7-dimethoxy-1-methyl-4-phenyl-cyclohepta-1,3,5-triene
  参考文献：
  名称：

  Regioselective synthesis of substituted tropones and azulenes using anodic oxidation of cycloheptatriene systems as the key reaction

  摘要：

  Regioselective synthesis of di- and trisubstituted tropones has been attained by utilizing anodic oxidation of cycloheptatriene systems as the key reaction. This anodic oxidation has also been found to be useful for the regioselective synthesis of mono- and disubstituted azulenes.

  DOI：

  10.1016/s0040-4039(00)74254-7

文献信息

• Regioselective synthesis of substituted tropones and azulenes using anodic oxidation of cycloheptatriene systems as the key reaction
  作者：Tatsuya Shono、Toshio Okada、Tsuyoshi Furuse、Shigenori Kashimura、Tetsuo Nozoe、Hirofumi Maekawa

  DOI：10.1016/s0040-4039(00)74254-7

  日期：1992.7

  Regioselective synthesis of di- and trisubstituted tropones has been attained by utilizing anodic oxidation of cycloheptatriene systems as the key reaction. This anodic oxidation has also been found to be useful for the regioselective synthesis of mono- and disubstituted azulenes.