Trimethyl-(4,4,5,5-tetraethyl-10,10-dimethyl-11-trimethylsilyl-4,5,10-trisilabicyclo[6.3.0]undeca-1(11),8-dien-2,6-diyn-9-yl)silane | 161615-63-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Trimethyl-(4,4,5,5-tetraethyl-10,10-dimethyl-11-trimethylsilyl-4,5,10-trisilabicyclo[6.3.0]undeca-1(11),8-dien-2,6-diyn-9-yl)silane
• CAS: 161615-63-0
• 化学式: C₂₄H₄₄Si₅
• 分子量: 473.041
• InChiKey: VLCFTPBDBBMKGI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.29
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Trimethyl-(4,4,5,5-tetraethyl-10,10-dimethyl-11-trimethylsilyl-4,5,10-trisilabicyclo[6.3.0]undeca-1(11),8-dien-2,6-diyn-9-yl)silane 、 iron pentacarbonyl 以 苯 为溶剂， 以87%的产率得到
  参考文献：
  名称：

  Polymeric Organosilicon Systems. 30. Preparation and Properties of Polymers Containing Iron(0)-Complex-Coordinated Silole Units

  摘要：

  UV irradiation of poly[(tetraethyldisilanylene)(3,4-diethynylenesilole)] in the presence of an excess of Fe(CO)(5) led to the formation of Fe(CO)(3)-coordinated silole units in the polymer backbone. The ratio of the Fe(CO)(3)-coordinated and noncoordinated units in the resulting polymer was determined to be 2:1 by H-1 NMR spectrometry. Similar treatment of poly[(tetramethyldisilanylene)(3,4-diethynylenesilole)] also afforded the corresponding Fe(CO)(3)-coordinated polymer. The polymers with Fe(CO)(3)-coordinated silole units exhibit slightly red-shifted UV absorption bands, relative to the parent noncoordinated polymers. When doped with FeCl3 vapor, the Fe(CO)(3)-coordinated polymers became semiconducting with conductivities on the order of 10(-5) S/cm, much higher than the conductivities of the parent polymers doped with FeCl3, which were determined to be less than 10(-8) S/cm. Crystal structures of two model compounds having Fe(CO)(3)-coordinated or noncoordinated 3,4-diethynylenesilole units were determined by X-ray crystallography, which suggest enhanced pi-conjugation in the Fe(CO)(3)-coordinated 3,4-diethynylenesilole ring as compared with the noncoordinated one.

  DOI：

  10.1021/om9805943

文献信息

• Polymeric Organosilicon Systems. 30. Preparation and Properties of Polymers Containing Iron(0)-Complex-Coordinated Silole Units
  作者：Joji Ohshita、Takeshi Hamaguchi、Eiji Toyoda、Atsutaka Kunai、Kenji Komaguchi、Masaru Shiotani、Mitsuo Ishikawa、Akinobu Naka

  DOI：10.1021/om9805943

  日期：1999.4.1

  UV irradiation of poly[(tetraethyldisilanylene)(3,4-diethynylenesilole)] in the presence of an excess of Fe(CO)(5) led to the formation of Fe(CO)(3)-coordinated silole units in the polymer backbone. The ratio of the Fe(CO)(3)-coordinated and noncoordinated units in the resulting polymer was determined to be 2:1 by H-1 NMR spectrometry. Similar treatment of poly[(tetramethyldisilanylene)(3,4-diethynylenesilole)] also afforded the corresponding Fe(CO)(3)-coordinated polymer. The polymers with Fe(CO)(3)-coordinated silole units exhibit slightly red-shifted UV absorption bands, relative to the parent noncoordinated polymers. When doped with FeCl3 vapor, the Fe(CO)(3)-coordinated polymers became semiconducting with conductivities on the order of 10(-5) S/cm, much higher than the conductivities of the parent polymers doped with FeCl3, which were determined to be less than 10(-8) S/cm. Crystal structures of two model compounds having Fe(CO)(3)-coordinated or noncoordinated 3,4-diethynylenesilole units were determined by X-ray crystallography, which suggest enhanced pi-conjugation in the Fe(CO)(3)-coordinated 3,4-diethynylenesilole ring as compared with the noncoordinated one.