3-[2-[2-(2-甲氧基乙氧基)乙氧基]乙氧基]丙烷-1,2-二醇 | 95535-29-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 中文名称: 3-[2-[2-(2-甲氧基乙氧基)乙氧基]乙氧基]丙烷-1,2-二醇
• 英文名称: (R)(S)-4,7,10,13-tetraoxy-1,2-tetradecanediol
• 英文别名: 2,5,8,11-Tetraoxatetradecane-13,14-diol；3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]propane-1,2-diol
• CAS: 95535-29-8
• 化学式: C₁₀H₂₂O₆
• 分子量: 238.281
• InChiKey: ZZWUTHDEIXYWSO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.7
• 重原子数：
  16
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3,4-二甲氧基噻吩 、 3-[2-[2-(2-甲氧基乙氧基)乙氧基]乙氧基]丙烷-1,2-二醇 、 二氯甲烷 在 氮 、 aqueous solution 、 碳酸氢钠 、 氯化钠 、 magnesium sulfate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以Pure 2-{2-[2-(2-methoxy-ethoxy)-ethoxy]-ethoxymethyl}-2,3-dihydro-thieno[3,4-b][1,4]dioxine was finally obtained by vacuum distillation的产率得到2-(2,5,8,11-Tetraoxadodecan-1-yl)-2,3-dihydrothieno[3,4-b][1,4]dioxine
  参考文献：
  名称：

  New 3,4-alkylenedioxy-thiophene copolymers

  摘要：

  一种水分散体，包含至少一种在25℃下水溶性小于2.2 g/L的3,4-亚烷二氧基噻吩共聚物，与至少一种在25℃下水溶性大于等于2.2 g/L的3,4-亚烷二氧基噻吩共聚物和一个多阴离子；其制备方法；用于涂层的使用；包含该水分散体的印刷油墨；包含至少一种在25℃下水溶性小于2.2 g/L的3,4-亚烷二氧基噻吩共聚物，与至少一种在25℃下水溶性大于等于2.2 g/L的3,4-亚烷二氧基噻吩共聚物和一个多阴离子的导电层，由其水分散体衍生；以及包含至少一种在25℃下水溶性小于2.2 g/L的3,4-亚烷二氧基噻吩共聚物，与至少一种在25℃下水溶性大于等于2.2 g/L的3,4-亚烷二氧基噻吩共聚物和一个多阴离子的抗静电层，由其水分散体衍生。

  公开号：

  US20050009986A1
• 作为产物：
  描述：

  1-(2氯乙氧基)-2-(2-甲氧基乙氧基)乙烷 、 丙酮缩甘油 在 四丁基溴化铵 sodium hydroxide 、 硫酸 作用下， 生成 3-[2-[2-(2-甲氧基乙氧基)乙氧基]乙氧基]丙烷-1,2-二醇
  参考文献：
  名称：

  Chiellini, Emo; Nieri, Paolo; Galli, Giancarlo, Molecular Crystals and Liquid Crystals (1969-1991), 1984, vol. 113, p. 213 - 224

  摘要：

  DOI：

文献信息

• Process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer
  申请人：Louwet Frank

  公开号：US20050245723A1

  公开（公告）日：2005-11-03

  A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): in which R 1 and R 2 independently of one another represent hydrogen or a C 1-5 -alkyl group or together form an optionally substituted C 1-5 -alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction is medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous or non-aqueous solution or dispersion comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer.

  制备含有结构单元式(I)的聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液的工艺，其中R1和R2独立地表示氢或C1-5烷基或一起形成一个可选择取代的C1-5烷基残基，包括以下步骤：在惰性气氛下，在存在聚阴离子的反应介质中使用引发剂制备聚噻吩或噻吩共聚物，在氧化或还原条件下，当添加少于每升反应介质中3毫克氧时，制备得到水溶液或非水溶液或分散液；使用含有聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液的水溶液或非水溶液或分散液涂覆物体；包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液的可印刷浆料；以含有聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液制备的导电层或抗静电层。
• Process for preparing an aqueous or non-aqueous solution or dispersion of a polythionphene or thiophene copolymer
  申请人：Agfa-Gevaert

  公开号：US20030211331A1

  公开（公告）日：2003-11-13

  A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): 1 in which R 1 and R 2 independently of one another represent hydrogen or a C 1-5 -alkyl group or together form an optionally substituted C 1-5 -alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous or non-aqueous solution or dispersion comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer.

  一种制备含有式(I)中所述结构单元的聚噻吩或噻吩共聚物的水性或非水性溶液或分散液的方法，其中R1和R2独立地表示氢或C1-5烷基或共同形成一个可选的取代的C1-5烷基残基，包括以下步骤：在惰性气氛下，在存在聚阴离子的反应介质中使用引发剂制备聚噻吩或噻吩共聚物，在氧化或还原条件下，使得当添加少于每升反应介质中3毫克的氧气时，反应介质中存在氧气；由此制备的水性或非水性溶液或分散液；使用含有聚噻吩或噻吩共聚物的水性或非水性分散液或溶液涂覆物体；含有聚噻吩或噻吩共聚物的水性或非水性溶液或分散液的可印刷浆料；使用含有聚噻吩或噻吩共聚物的水性或非水性溶液或分散液制备的导电或抗静电层。
• 3,4-alkylenedioxy-thiophene copolymers
  申请人：AGFA-GEVAERT

  公开号：US20030149171A1

  公开（公告）日：2003-08-07

  An aqueous dispersion of a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion; a preparation process therefor; its use for coating; a printing ink containing the aqueous dispersion; an electro-conductive layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof; and an antistatic layer containing a copolymer of at least one 3,4-alkylenedioxy-thiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof.

  一种水分散体，包含至少一种在25°C下水溶性小于2.2 g/L的3,4-二烷基二氧硫杂吡咯化合物的共聚物，与至少一种在25°C下水溶性大于等于2.2 g/L的3,4-二烷基二氧硫杂吡咯化合物和一种聚阴离子；其制备方法；用于涂层的使用；含有该水分散体的印刷油墨；包含至少一种在25°C下水溶性小于2.2 g/L的3,4-二烷基二氧硫杂吡咯化合物的共聚物，与至少一种在25°C下水溶性大于等于2.2 g/L的3,4-二烷基二氧硫杂吡咯化合物和一种聚阴离子的电导层，以及包含该水分散体的共聚物的抗静电层。
• Aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer
  申请人：Agfa-Gevaert

  公开号：US07378039B2

  公开（公告）日：2008-05-27

  A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction is medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous or non-aqueous solution or dispersion comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer.

  一种制备聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液的方法，其含有结构单元如公式（I）所示：其中R1和R2分别独立地表示氢或C1-5烷基或共同形成一个可选的取代的C1-5烷基残基，包括以下步骤：在惰性气氛下，在存在聚阴离子的反应介质中使用引发剂制备聚噻吩或噻吩共聚物，在氧化或还原条件下，在反应介质中添加少于3毫克的氧气/升反应介质的情况下，制备所述的水溶液或非水溶液或分散液；使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液涂覆物体；包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液的可打印浆料；以及使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散液制备的导电或抗静电层。
• Process for preparing an aqueous solution or dispersion of a polythiophene or thiophene copolymer
  申请人：AGFA-GEVAERT

  公开号：EP1323764A1

  公开（公告）日：2003-07-02

  A process for preparing an aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I) : in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous solution or dispersion prepared therewith; the use of an aqueous dispersion or solution comprising the aqueous dispersion or solution of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous dispersion or solution of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous dispersion comprising the aqueous dispersion of a polythiophene or thiophene copolymer.

  一种制备聚噻吩或噻吩共聚物水溶液或分散液的工艺，该聚噻吩或噻吩共聚物含有符合式 (I) 的结构单元： 其中 R1 和 R2 各自代表氢或 C1-5-烷基或共同形成任选取代的 C1-5- 烷基残基，包括以下步骤：在惰性气氛下，在氧化或还原条件下，在有聚阴离子存在的反应介质中，用引发剂制备聚噻吩或噻吩共聚物，当加入所述引发剂时，每升反应介质中的氧气含量少于 3 毫克；用其制备的水溶液或分散液；使用包含聚噻吩或噻吩共聚物水性分散体或水溶液的水性分散体或水溶液涂覆物体；包含聚噻吩或噻吩共聚物水性分散体或水溶液的可印刷浆料；以及使用包含聚噻吩或噻吩共聚物水性分散体的水性分散体制备的导电层或抗静电层。