甲醛与2-甲酚的聚合物 | 25053-96-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 甲醛与2-甲酚的聚合物
• 中文别名: 甲醛与甲基苯酚的聚合物；甲酚醛树酯
• 英文名称: cresol formaldehyde
• 英文别名: Formaldehyde cresol；formaldehyde;2-methylphenol
• CAS: 25053-96-7；9016-83-5；102324-87-8
• 化学式: CH₂O*C₇H₈O
• 分子量: 138.166
• InChiKey: VOOLKNUJNPZAHE-UHFFFAOYSA-N

物化性质

• 熔点：
  110 °C

计算性质

• 辛醇/水分配系数(LogP)：
  1.52
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  邻甲酚 、 聚合甲醛 、 硫酸 反应 0.83h， 生成 甲醛与2-甲酚的聚合物
  参考文献：
  名称：

  Process for the production of phenol silicate compounds and their

  摘要：

  苯酚化合物和硅酸会在加热时与适当的碱性催化剂发生化学反应，产生苯酚硅酸盐。然后，苯酚硅酸盐化合物与醛化合物进行化学反应，形成缩合产物。

  公开号：

  US04032511A1

文献信息

• [EN] PHOSPHORUS-CONTAINING COMPOUNDS USEFUL FOR MAKING HALOGEN-FREE, IGNITION-RESISTANT POLYMERS<br/>[FR] COMPOSÉS PHOSPHORÉS UTILES POUR LA FABRICATION DE POLYMÈRES RÉSISTANT À L'INFLAMMATION ET EXEMPTS D'HALOGÈNE
  申请人：DOW GLOBAL TECHNOLOGIES INC

  公开号：WO2005118604A1

  公开（公告）日：2005-12-15

  Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H-P= 0 ; the group P-H and the group P-OH; and (B) at least one compound having the following Formula (I): Formula (I) [R'(Y)m']m(X - O - R')n wherein R' is an organic group; Y is a functional group selected from hydroxy, carboxylic acid, carboxylate, acid 15 anhydride, and amine; -SH, -SO3H, -CONH2, -NHCOOR, phosphite and phosphinate groups X is a hydrocarbylene group; R' is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m', m and n are, independently, numbers equal to or greater than 1. These compounds are useful for making flame retardant epoxy and polyurethane resins and ignition resistant thermoplastic resins, each of which is useful for a variety of end uses requiring flame retardancy or ignition resistance. Flame retardant epoxy resins may be used to make electrical laminates. Flame retardant polyurethane is useful for making rigid polyurethane foam used in construction and flexible polyurethane foam used to make vehicle upholstery. Ignition resistant thermoplastic resins are useful for making television cabinets, computer monitors, printer housings, automotive parts, and housings and parts for appliances. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.

  本发明揭示了一种含磷化合物，其可通过反应获得：(A)至少一种有机磷化合物，该有机磷化合物具有从H-P=0组中选择的基团；P-H基团和P-OH基团；和(B)至少一种具有以下化学式(I)的化合物：化学式(I) [R'(Y)m']m(X - O - R')n，其中R'是有机基团；Y是从羟基、羧酸、羧酸盐、酸酐和胺中选择的功能基团；-SH、-SO3H、-CONH2、-NHCOOR、磷酸酯和亚磷酸盐基团；X是一个烃基烷基；R'是氢或具有1至8个碳原子的烃基基团，R是具有1至12个碳原子的烷基或芳基基团；m'、m和n分别是大于或等于1的数字。这些化合物可用于制备阻燃环氧树脂和聚氨酯树脂以及防火热塑性树脂，每种树脂都可用于各种需要阻燃性或防火性的最终用途。阻燃环氧树脂可用于制造电气层压板。阻燃聚氨酯树脂可用于制造建筑中使用的刚性聚氨酯泡沫和用于制造汽车座椅的柔性聚氨酯泡沫。防火热塑性树脂可用于制造电视柜、计算机显示器、打印机外壳、汽车零部件以及电器外壳和零部件。本发明特别适用于需要或期望低溴或低卤素含量的最终用途应用中。
• CURATIVES FOR EPOXY ADHESIVE COMPOSITIONS
  申请人：Dershem Stephen M.

  公开号：US20100113643A1

  公开（公告）日：2010-05-06

  The invention provides epoxy and oxetane compositions including the novel acyloxy and N-acyl curing agents described herein. Use of invention curing agents result in cured adhesive compositions with remarkably increased adhesion and reduced hydrophilicity when compared to resins cured with other types of curing agents. Furthermore, the curatives of this invention do not interfere with free-radical cure and are thus suited for use in hybrid cure thermoset compositions.

  该发明提供了包括新型酰氧基和N-酰基固化剂的环氧树脂和氧环烷组合物。使用该发明的固化剂可使胶粘剂组合物固化后的粘附性大大增加，并且与用其他类型的固化剂固化的树脂相比，其亲水性减少。此外，该发明的固化剂不会干扰自由基固化，因此适用于混合固化热固性组合物的使用。
• [EN] 1,4-HYDROQUINONE FUNCTIONALIZED PHOSPHYNATES AND PHOSPHONATES<br/>[FR] PHOSPHINATES ET PHOSPHONATES FONCTIONNALISÉS PAR DES GROUPEMENTS DE TYPE 1,4-HYDROQUINONE
  申请人：CHEMTURA CORP

  公开号：WO2006034445A1

  公开（公告）日：2006-03-30

  There is presented novel 1,4-hydroquinone derivatized phosphinates and phosphonates. The novel compositions here presented are useful as polymer curing agents and as flame retardants. Where R, R’ each independently are the same or different aryl, aralkyl or alkyl comprising from one to 15 carbon atoms.

  提供了新颖的1,4-羟基苯醌衍生的膦酸酯和膦酸盐。这里提供的新颖组合物可用作聚合物固化剂和阻燃剂。其中，R和R'各自独立地是相同或不同的含有1至15个碳原子的芳基、芳基烷基或烷基。
• SULFONATE COMPOUND, PHOTOACID GENERATOR, AND RESIN COMPOSITION FOR PHOTOLITHOGRAPHY
  申请人：SAN-APRO LIMITED

  公开号：US20170233336A1

  公开（公告）日：2017-08-17

  Provided are: a non-ionic photoacid generator containing a sulfonate compound having a high photosensitivity to i lines, exhibiting excellent heat-resistance stability, and exhibiting excellent solubility in a hydrophobic material; and a resin composition for photolithography containing the same. The present invention is a sulfonate compound characterized by being represented by general formula (1). [In formula (1), R1 represents an aryl group having 6 to 18 carbon atoms or a heterocyclic hydrocarbon group having 4 to 20 carbon atoms. R2 represents a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, an alkynyl group having 2 to 18 carbon atoms, or an aryl group having 6 to 18 carbon atoms. R3 represents a hydrocarbon group having 1 to 18 carbon atoms (in which some or all hydrogen atoms may be substituted with fluorine).]

  提供的是：一种非离子光酸发生剂，含有对i线具有高光敏度的磺酸化合物，表现出优异的耐热稳定性，并在疏水材料中表现出优异的溶解性；以及含有该化合物的光刻树脂组合物。本发明是一种磺酸化合物，其特征在于由通式（1）表示。[在式（1）中，R1表示具有6至18个碳原子的芳基基团或具有4至20个碳原子的杂环烃基团。R2表示氢原子，具有1至18个碳原子的烷基基团，具有2至18个碳原子的烯基基团，具有2至18个碳原子的炔基基团或具有6至18个碳原子的芳基基团。R3表示具有1至18个碳原子的烃基团（其中一些或全部氢原子可以被氟代替）。]
• 1, 4-Hydroquinone functionalized phosphinates and phosphonates
  申请人：Hanson V. Mark

  公开号：US20060099458A1

  公开（公告）日：2006-05-11

  There is presented novel 1,4-hydroquinone derivatized phosphinates and phosphonates. The novel compositions here presented are useful as polymer curing agents and as flame retardants.

  这里提出了新型的1,4-羟基苯醌衍生的膦酸盐和膦酸酯。这些新型组合物可用作聚合物固化剂和阻燃剂。