An unprecedented oxidant-mediated reductive amination of tertiary anilines and aldehydes without external reducing agents was developed via the nucleophilic attack of the oxygen atom of the carbonyl group to in situ generated iminium ions, in which tertiary anilines were used as both nitrogen source and reducing agent for the first time.
通过羰基氧原子对原位生成的亚
氨离子的亲核攻击,开发了一种前所未有的氧化剂介导的叔
苯胺和醛的还原胺化反应,无需外加还原剂,其中叔
苯胺首次同时用作氮源和还原剂。