phenyl 3-O-benzyl-2,6-di-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside | 945391-33-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: phenyl 3-O-benzyl-2,6-di-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside
• CAS: 945391-33-3
• 化学式: C₁₃₄H₁₉₈O₄₈S
• 分子量: 2609.08
• InChiKey: MAMIQEKKZIKRPB-IFTNRTSRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.87
• 重原子数：
  183.0
• 可旋转键数：
  56.0
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  516.76
• 氢给体数：
  1.0
• 氢受体数：
  49.0

反应信息

• 作为产物：
  描述：

  、 phenyl 2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside 、 phenyl 3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside 在 三氟化硼乙醚 active moleculae sieve 4A 作用下， 以 二氯甲烷 为溶剂， -30.0 ℃ 、0.13 Pa 条件下， 反应 14.5h， 以10%的产率得到phenyl 3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-3-O-benzyl-2,6-di-O-pivaloyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-β-D-glucopyranosyl-[1-4]-2,3,6,-tri-O-methyl-β-D-glcopyranosyl-[1-4]-2,3,6-tri-methyl-β-D-glucopyranosyl-[1-4]-2,3,6-tri-O-methyl-1-thio-β-D-glucopyranoside
  参考文献：
  名称：

  WO2006/67883

  摘要：

  公开号：