2-(2,6-Dimethylhept-6-en-3-yn-2-yloxymethyl)oxirane | 768370-45-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(2,6-Dimethylhept-6-en-3-yn-2-yloxymethyl)oxirane
• CAS: 768370-45-2
• 化学式: C₁₂H₁₈O₂
• 分子量: 194.274
• InChiKey: KHZNXYGFWYLHCY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(2,6-Dimethylhept-6-en-3-yn-2-yloxymethyl)oxirane 、 二乙胺 以 水 、 1,4-二氧六环 为溶剂， 以66.6%的产率得到1-(diethylamino)-3-(2,6-dimethylhept-6-en-3-yn-2-yloxy)propan-2-ol
  参考文献：
  名称：

  Allylacetylenes and their derivatives as inhibitors of steel corrosion in sulfuric acid

  摘要：

  New functionalized derivatives of allylacetylenes were prepared, and their ability to inhibit corrosion of St.3 low-carbon steel in 5 N sulfuric acid was studied. The effectiveness of inhibition of steel corrosion was studied in relation to the structure of acetylene derivatives, their concentration, and temperature of acidic medium.

  DOI：

  10.1134/s1070427206110176
• 作为产物：
  描述：

  1-chloro-3-(2,6-dimethylhept-6-en-3-yn-2-yloxy)propan-2-ol 在 氢氧化钾 作用下， 以 乙醚 为溶剂， 以78.2%的产率得到2-(2,6-Dimethylhept-6-en-3-yn-2-yloxymethyl)oxirane
  参考文献：
  名称：

  Allylacetylenes and their derivatives as inhibitors of steel corrosion in sulfuric acid

  摘要：

  New functionalized derivatives of allylacetylenes were prepared, and their ability to inhibit corrosion of St.3 low-carbon steel in 5 N sulfuric acid was studied. The effectiveness of inhibition of steel corrosion was studied in relation to the structure of acetylene derivatives, their concentration, and temperature of acidic medium.

  DOI：

  10.1134/s1070427206110176