sodium 2-isopropoxyethoxide | 111454-73-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: sodium 2-isopropoxyethoxide
• 英文别名: Sodium;2-propan-2-yloxyethanolate
• CAS: 111454-73-0
• 化学式: C₅H₁₁O₂*Na
• 分子量: 126.131
• InChiKey: UHFILTGBPVEWNM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.22
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  32.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  copper acetylacetonate 、 sodium 2-isopropoxyethoxide 以 甲苯 为溶剂， 以96.5%的产率得到{(copper)(2-isopropoxyethoxide)(acetylacetonate)}4
  参考文献：
  名称：

  Reactions between copper(II) β-diketonates and metal alkoxides as a route to soluble and volatile copper(II) oxide precursors: Synthesis and molecular structure of Cu4(μ3,η1-OC2H4IOiPr)4(acac)4 and (acac)Cu(μ-OSiMe3)2Al(OSiMe3)2

  摘要：

  Reactions between Cu(acac)2 and metal alkoxides such as [Y(OC2H4OR)3]m (R = Me, (i)Pr) and [Al(OSiMe3)3]2 were investigated. The reactions afforded, respectively, Cu4(mu-3,eta-1-OC2H4OiPr)4(acaC)4 (1) and (acac)Cu(mu-OSiMe3)2Al(OSiMe3)2 (2) for the copper(II) species. The metal-oxygen framework in 1 corresponds to a cubane structure in which four corners are occupied by mu-3,eta-1 alkoxide ligands; the metals are pentacoordinated. The heterometallic alkoxide 2 exists as two conformers in the solid state which differ mainly in the Al-O-Si bond angles involving the terminal siloxo groups: 145-degrees av. for 2a and 170-degrees av. for 2b. Both copper(II) compounds are volatile as well as hydrolysable.

  DOI：

  10.1016/s0277-5387(00)83279-9

文献信息

• Vompe, A. F.; Ivanova, L. V., Journal of Organic Chemistry USSR (English Translation), 1982, p. 943 - 947
  作者：Vompe, A. F.、Ivanova, L. V.

  DOI：——

  日期：——