(Ξ)-2-((3aR)-4c-methanesulfonyloxy-2,2-dimethyl-(3ar,8at,8bc)-3a,4,5,6,8a,8b-hexahydro-[1,3]dioxolo[4,5-e]indazol-5at-yl)-oxiranecarboxylic acid methylamide | 26681-58-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (Ξ)-2-((3aR)-4c-methanesulfonyloxy-2,2-dimethyl-(3ar,8at,8bc)-3a,4,5,6,8a,8b-hexahydro-[1,3]dioxolo[4,5-e]indazol-5at-yl)-oxiranecarboxylic acid methylamide
• CAS: 26681-58-3
• 化学式: C₁₅H₂₃N₃O₇S
• 分子量: 389.43
• InChiKey: YJUIJXPIOKKSQC-ZBKLHVQGSA-N

反应信息

• 作为产物：
  描述：

  重氮甲烷 、 2-((3aR)-7c-methanesulfonyloxy-2,2-dimethyl-(3ar,7ac)-3a,6,7,7a-tetrahydro-benzo[1,3]dioxol-5-yl)-N-methyl-2-oxo-acetamide 生成 (Ξ)-2-((3aR)-4c-methanesulfonyloxy-2,2-dimethyl-(3ar,8at,8bc)-3a,4,5,6,8a,8b-hexahydro-[1,3]dioxolo[4,5-e]indazol-5at-yl)-oxiranecarboxylic acid methylamide
  参考文献：
  名称：

  Synthetic intermediates potentially useful for the synthesis of tetrodotoxin and derivatives. III. Synthesis of a key lactone intermediate from shikimic acid

  摘要：

  DOI：

  10.1021/jo00800a025