[(6-picolynato)(2,6-bis(dimethylamino)methylpyridine)ruthenium(II)] monohydrate | 1400697-73-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(6-picolynato)(2,6-bis(dimethylamino)methylpyridine)ruthenium(II)] monohydrate
• 英文别名: [Ru(NNN)(6-picolinato)]*H2O
• CAS: 1400697-73-5
• 化学式: C₁₉H₂₅N₅O₃Ru
• 分子量: 472.509
• InChiKey: RMCHQMPVGPJDHL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(6-picolynato)(2,6-bis(dimethylamino)methylpyridine)ruthenium(II)] monohydrate 在 盐酸 作用下， 以 氘代氯仿 为溶剂， 生成 [(6-picolynato)(2,6-bis(dimethylamino)methylpyridine)ruthenium(II)] monohydrate
  参考文献：
  名称：

  Synthesis and structural characterization of novel ruthenium(II) complexes bearing hydroxypicolinato ligands

  摘要：

  A series of ruthenium(II) complexes bearing hydroxypicolinato ligands was synthesized and characterized. The reaction of [Ru(NNN)(pic-6OH)Cl] (1), where NNN is 2,6-bis(dimethylamino)methylpyridine and featuring the 6-hydroxypicolinate ligand (pic-6OH), with (KOBu)-Bu-t in acetonitrile produced [Ru(NNN)(CH3CN)(2-pyridonato)] (4), in which pic-6OH was converted into its pyridonato tautomer form. The pyridonato-ligated complex 4 reacts with HCl to quantitatively regenerate 1, thus the interconversion between the pyridinol and pyridonato forms of hydroxypicolinate was successfully achieved using a Ru(II) complex supported by the NNN-pincer ligand. The complexes [Ru(NNN)(pic-3OH)Cl] (2) and [Ru(NNN)(pic)Cl] (3) were also prepared and characterized for comparison. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.07.058
• 作为产物：
  描述：

  [(6-picolynato)(2,6-bis(dimethylamino)methylpyridine)ruthenium(II)] monohydrate 、 乙腈 在 potassium tert-butylate 作用下， 反应 12.0h， 以64%的产率得到[(6-picolynato)(2,6-bis(dimethylamino)methylpyridine)ruthenium(II)] monohydrate
  参考文献：
  名称：

  Synthesis and structural characterization of novel ruthenium(II) complexes bearing hydroxypicolinato ligands

  摘要：

  A series of ruthenium(II) complexes bearing hydroxypicolinato ligands was synthesized and characterized. The reaction of [Ru(NNN)(pic-6OH)Cl] (1), where NNN is 2,6-bis(dimethylamino)methylpyridine and featuring the 6-hydroxypicolinate ligand (pic-6OH), with (KOBu)-Bu-t in acetonitrile produced [Ru(NNN)(CH3CN)(2-pyridonato)] (4), in which pic-6OH was converted into its pyridonato tautomer form. The pyridonato-ligated complex 4 reacts with HCl to quantitatively regenerate 1, thus the interconversion between the pyridinol and pyridonato forms of hydroxypicolinate was successfully achieved using a Ru(II) complex supported by the NNN-pincer ligand. The complexes [Ru(NNN)(pic-3OH)Cl] (2) and [Ru(NNN)(pic)Cl] (3) were also prepared and characterized for comparison. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.07.058