[(E)-4-cyclohexylbut-2-enyl]cyclohexane | 1314476-62-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: [(E)-4-cyclohexylbut-2-enyl]cyclohexane
• CAS: 1314476-62-4
• 化学式: C₁₆H₂₈
• 分子量: 220.398
• InChiKey: IYIFWWSRYPKJDE-BQYQJAHWSA-N

物化性质

• 沸点：
  306.0±9.0 °C(Predicted)
• 密度：
  0.870±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  丙烯基环庚烷 在 bis[1,1-di(trifluoromethyl)ethoxy][(2,6-diisopropylphenyl)imino](2-methyl-2-phenylpropylidene)molybdenum 、 乙烯 作用下， 22.0 ℃ 、405.33 kPa 条件下， 反应 0.25h， 以78%的产率得到[(E)-4-cyclohexylbut-2-enyl]cyclohexane
  参考文献：
  名称：

  Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures

  摘要：

  Monoaryloxide-pyrrolide (MAP) complexes of molybdenum were employed for the selective ethenolysis of 1,2-disubstituted Z olefins in the presence of the corresponding E olefins. Reactions were performed in the presence of 0.02-3.0 mol % catalyst at 22 degrees C under 20 atm ethylene. We have demonstrated that the Z isomer of an easily accessible E:Z mixture can be destroyed through ethenolysis and the E alkene thereby isolated readily in high yield and exceptional stereoisomeric purity.

  DOI：

  10.1021/ja205002v

文献信息

• HIGHLY Z-SELECTIVE OLEFINS METATHESIS
  申请人：Schrock Richard R.

  公开号：US20110077421A1

  公开（公告）日：2011-03-31

  The present invention relates generally to catalysts and processes for the Z-selective formation of internal olefin(s) from terminal olefin(s) via homo-metathesis reactions.

  本发明通常涉及催化剂和过程，用于通过同型交换反应从末端烯烃中Z-选择性地形成内部烯烃。
• Highly Z-selective olefins metathesis
  申请人：Massachusetts Institute of Technology

  公开号：US09079173B2

  公开（公告）日：2015-07-14

  The present invention relates generally to catalysts and processes for the Z-selective formation of internal olefin(s) from terminal olefin(s) via homo-metathesis reactions.

  本发明涉及催化剂和过程，用于通过同型烯烃交换反应从末端烯烃中Z-选择性地形成内部烯烃。
• Electrochemical Synthesis of trans-Olefins from Buta-1,3-dienes and Alkyl Halides
  作者：Chao Yang、Wujiong Xia、Haoxiang Zhang、Lin Guo

  DOI：10.1055/a-2006-1285

  日期：——

  electrochemical alkylation reaction of buta-1,3-diene derivatives with alkyl halides has been developed, generating highly selective trans-olefins as major products. This method exhibits significant advantages, including simple operation, mild conditions, and convenience of scale-up, and provides a novel route for the synthesis of trans-olefins.

  已开发出丁-1,3-二烯衍生物与卤代烷的简便电化学烷基化反应，生成高选择性反式烯烃作为主要产物。该方法具有操作简单、条件温和、放大方便等显着优点，为反式烯烃的合成提供了一条新路线。
• WARWEL, S.;RIDDER, H.;HACHEN, G., CHEM.-ZTG, 1983, 107, N 4, 115-120
  作者：WARWEL, S.、RIDDER, H.、HACHEN, G.

  DOI：——

  日期：——