| 1196061-70-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 1196061-70-7
• 化学式: C₄₃H₃₅N₅O₄Zn
• 分子量: 751.172
• InChiKey: SJGDDPAYEYANEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  α,α,α-三联吡啶 、 1,10-亚铁试剂(邻二氮杂菲),2,9-二(2,6-二甲氧苯基)- 、 2,9-dimesityl-1,10-phenanthroline 、 tetrakis(actonitrile)copper(I) hexafluorophosphate 、 zinc trifluoromethanesulfonate 以 乙腈 为溶剂， 生成 、 (2,9-dimesityl-1,10-phenanthroline)(1,10-phenanthroline)copper(I)
  参考文献：
  名称：

  From 2-Fold Completive to Integrative Self-Sorting: A Five-Component Supramolecular Trapezoid

  摘要：

  The amalgamation of two incomplete self-sorting processes into a process that makes quantitative use of all members of the library is described by 2-fold completive self-sorting. Toward this goal, individual metal-ligand binding scenarios were optimized for high thermodynamic stability and best selectivity, by screening a variety of factors, such as steric and electronic effects, pi-pi interactions, and metal-ion specifics. Using optimized, heteroleptic metal-ligand binding motifs, a library of four different ligands (1, 2, 3, 4) and two different metal ions (Zn2+, Cu+) was set up to assess 2-fold completive self-sorting. Out of 20 different combinations, the self-sorting library ended up with only two metal-ligand complexes in basically quantitative yield. To demonstrate the value of 2-fold completive self-sorting for the formation of nanostructures, the optimized, highly selective binding motifs were implemented into three polyfunctional ligands. Their integrative self-sorting in the presence of Zn2+ and Cu+ led to the clean formation of the supramolecular trapezoid T, a simple but still unknown supramolecular architecture. The dynamic trapezoid T consists of three different ligands with four different donor-acceptor interactions. Its structure was established by H-1 NMR spectroscopy, electrospray ionization mass spectroscopy, and differential pulse voltammetry (DPV) and by exclusion of alternative structures.

  DOI：

  10.1021/ja907185k