2,2-difluoro-5-methoxy-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinine | 1186339-54-7

• 英文名称: 2,2-difluoro-5-methoxy-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinine
• CAS: 1186339-54-7
• 化学式: C₆H₉BF₂O₃
• 分子量: 177.943
• InChiKey: AWXLVDMFKBILPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  HacacOMe 在 硼酸三丁酯 、 三氟化硼乙醚 作用下， 以 乙醚 为溶剂， 反应 3.0h， 以60%的产率得到2,2-difluoro-5-methoxy-4,6-dimethyl-2H-1l3,3,2l4-dioxaborinine
  参考文献：
  名称：

  α-substituted boron difluoride acetylacetonates

  摘要：

  By treatment of a-substituted acetylacetone derivatives with boron trifluoride etherate a series of earlier unknown boron difluoride complexes is obtained. The series includes binuclear complexes containing boron in the chelate fragment connected via sulfur or selenium atom. Gas chromatographic and spectral characteristics of the obtained compounds were investigated. By means of chromato-mass spectrometry their reaction with hydrazine in acidic and alkaline media was studied.

  DOI：

  10.1134/s1070363208080094