4,4'-bis[2-(perfluorohexyl)ethoxy]-2,2'-bipyridine-1,1'-dioxide | 1251034-31-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,4'-bis[2-(perfluorohexyl)ethoxy]-2,2'-bipyridine-1,1'-dioxide
• CAS: 1251034-31-7
• 化学式: C₂₆H₁₄F₂₆N₂O₄
• 分子量: 912.367
• InChiKey: YBTILLMIXCXUOY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.64
• 重原子数：
  58.0
• 可旋转键数：
  17.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  72.34
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  4,4'-bis[2-(perfluorohexyl)ethoxy]-2,2'-bipyridine-1,1'-dioxide 在 三溴化磷 、 sodium hydroxide 作用下， 以 氯仿 、 水 为溶剂， 反应 3.0h， 以82%的产率得到4,4'-bis[2-(perfluorohexyl)ethoxy]-2,2'-bipyridine
  参考文献：
  名称：

  Synthesis of new CO2-soluble ruthenium(II) and cobalt(II) polypyridine complexes bearing fluorinated alkyl chains and their application to photoreduction of liq. CO2

  摘要：

  Eight types of new CO2-soluble or CO2-philic ruthenium(II) and cobalt(II) polypyridine complexes, namely, [M(F84OPh)(3)](BArF)(2), [M(F44OPh)(3)](BArF)(2), [M(F62Ph)(3)](BArF)(2), and [M(F62O)(3)](BArF)(2) (M = Ru or Co, BArF: tetrakis[3,5-bis(trifluoromethyl)phenyl]borate), were prepared from bipyridine derivatives bearing highly fluorinated alkyl chains and applied to the photoreduction of liq. CO2 under a high pressure of 6.8 MPa at 35 degrees C. All these complexes have higher philicity toward lig. CO2 than the corresponding complexes with PF6- as the counteranion. Using the Ru(II)-Co(II) systems of [M(F44OPh)(3)](BArF)(2) and [M(F62O)(3)](BArF)(2), direct photoreduction of CO2 was achieved without the use of any organic solvent. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2010.06.005
• 作为产物：
  描述：

  3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇 、 4,4-二硝基-2,2-联吡啶 N,N-二氧化物 在 氢化钾 作用下， 以 乙醚 为溶剂， 反应 32.0h， 以59%的产率得到4,4'-bis[2-(perfluorohexyl)ethoxy]-2,2'-bipyridine-1,1'-dioxide
  参考文献：
  名称：

  Synthesis of new CO2-soluble ruthenium(II) and cobalt(II) polypyridine complexes bearing fluorinated alkyl chains and their application to photoreduction of liq. CO2

  摘要：

  Eight types of new CO2-soluble or CO2-philic ruthenium(II) and cobalt(II) polypyridine complexes, namely, [M(F84OPh)(3)](BArF)(2), [M(F44OPh)(3)](BArF)(2), [M(F62Ph)(3)](BArF)(2), and [M(F62O)(3)](BArF)(2) (M = Ru or Co, BArF: tetrakis[3,5-bis(trifluoromethyl)phenyl]borate), were prepared from bipyridine derivatives bearing highly fluorinated alkyl chains and applied to the photoreduction of liq. CO2 under a high pressure of 6.8 MPa at 35 degrees C. All these complexes have higher philicity toward lig. CO2 than the corresponding complexes with PF6- as the counteranion. Using the Ru(II)-Co(II) systems of [M(F44OPh)(3)](BArF)(2) and [M(F62O)(3)](BArF)(2), direct photoreduction of CO2 was achieved without the use of any organic solvent. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2010.06.005