N-[bis(dimethylamino)phosphoryl]-N-methylmethanamine;cerium(3+);cyclopenta-1,3-diene | 213480-14-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: N-[bis(dimethylamino)phosphoryl]-N-methylmethanamine;cerium(3+);cyclopenta-1,3-diene
• CAS: 213480-14-9
• 化学式: C₆H₁₈N₃OP*C₁₅H₁₅Ce
• 分子量: 514.606
• InChiKey: QDNZVGDLRBTCAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六甲基磷酰三胺 、 三(氰基式二烯基)铈 以 正戊烷 为溶剂， 生成 N-[bis(dimethylamino)phosphoryl]-N-methylmethanamine;cerium(3+);cyclopenta-1,3-diene
  参考文献：
  名称：

  Synthesis and magnetic properties of (C5H5)3Ce·HMPA

  摘要：

  The 1:1 adduct (C5H5)(3)Ce . O=P(NMe2)(3) of cerium(III)-triscyclopentadienide with hexamethylphosphoric triamide (HMPA) was synthesized, isolated, purified and characterized by elemental analysis, IR- and H-1-NMR spectroscopy. The H-1-NMR spectrum obtained in solution in CDCl3 at room temperature exhibits a single signal for the Cp-proton at 5.6 ppm and a signal for the CH3-proton of the base HMPA at 0.49 ppm. The paramagnetic shift due to the Ce(III) ion could be evaluated by comparison to the corresponding signals of the homologous diamagnetic compound Cp3La . HMPA. The temperature-dependent paramagnetic susceptibility of the compound was measured within the temperature range from 4.2 up to 300 K. From the 1/chi(mol) vs. T-plot the empirical constant C=0.78 m(3) K mol(-1) was evaluated with a Curie-Weiss constant theta of -71 K. The temperature dependence of the magnetic moment (mu(eff)) is consistent with a Ce(III) ion. The ground state of the Ce ion is only partially populated. The magnetic moment at room temperature is 2.25 mu(B), an indication of covalency, as it has been observed for several Ce(III)-organometallics. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0925-8388(98)00444-7