| 886359-50-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 886359-50-8
• 化学式: C₁₆H₁₄N₆NiO₂*H₂O
• 分子量: 399.031
• InChiKey: SGQYDJKMWBBZCJ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  N',N''-bis[1-(pyridin-2-yl)ethylidene]oxalohydrazide 、 nickel(II) acetate tetrahydrate 以 水 、 异丙醇 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  A novel polymeric Cu(II) assemblage and a monomeric Ni(II) complex from a new easy-to-prepare flexible polytopic ligand: Synthesis, structural and magnetic studies

  摘要：

  The difference in coordination behavior of one new flexible polytopic ligand H2L (L = C16H14N6O2) has been examined with Cu(II) and Ni(II) acetate. It leads to the formation of a polynuclear pentacoordinated Cu(II) assemblage and a mononuclear four coordinated Ni(II) complex. Both the Compounds are characterized spectroscopically and electrochemically. In the complexes I and 2 the ligand binds the metal centers in trans- and cis-orientation (exo and endo-fashion), respectively. The polynuclear copper complex exhibits strong antiferromagnetic behavior at low temperature with J = -327 cm(-1) and DFT calculation is also carried Out for this complex. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.09.008