[copper(II)(salicylidene anthanilic acid(-2H)(2-))(1,10-phenanthroline)] | 66744-95-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [copper(II)(salicylidene anthanilic acid(-2H)(2-))(1,10-phenanthroline)]
• CAS: 66744-95-4
• 化学式: C₂₆H₁₇CuN₃O₃
• 分子量: 482.985
• InChiKey: GGSIVVWGRYTFAJ-CBNWXSEKSA-L

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 copper(II) choride dihydrate 、 salicylidene anthanilic acid(-2H)(2-) 以 甲醇 为溶剂， 以80%的产率得到[copper(II)(salicylidene anthanilic acid(-2H)(2-))(1,10-phenanthroline)]
  参考文献：
  名称：

  Synthesis, structure and properties of ternary copper(II) complexes of ONO donor Schiff base, imidazole, 2,2′-bipyridine and 1,10-phenanthroline

  摘要：

  Reaction of copper(II) salt with salicylidene anthanilic acid (SAA), a tridentate ligand and imidazole (ImH), a monodentate ligand or bidentate polypyridyl ligands like 2,2'-bipyridine (bipy) or 1,10-phenanthroline(phen) in MeOH:MeCN (1:1 V/V) yields [Cu(SAA)(ImH)] (1), [Cu(SAA)(bipy)]CH3CN (2) and [Cu(SAA)(phen)] (3) in similar to 80% yield. These complexes were characterized by elemental analysis, magnetic susceptibility, X-band e.p.r., electronic spectroscopy and cyclic voltammetry. All the reported complexes show g(parallel to) > g(perpendicular to) > 2.0023 and G values falling within the range of 2-4 are consistent with a d(x2-y2) ground state in a square planar or square pyramidal geometry. Single crystal X-ray analysis of 1 has revealed the presence of a distorted square planar geometry (N2O2) and 2 has revealed the presence of distorted square pyramidal (4 + 1) geometry. In both structures the ONO Schiff base occupies the basal plane. Magnetic susceptibility measurements at room temperature were in the range 1.79 +/- 0.01 BM. Superoxide dismutase (SOD) activity of the present complexes were also measured. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.06.017