[Rh(PMe3)(PPh3)(B(methimazolyl)3)]Cl | 874200-67-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Rh(PMe3)(PPh3)(B(methimazolyl)3)]Cl
• CAS: 874200-67-6
• 化学式: C₃₃H₃₉BN₆P₂RhS₃*Cl
• 分子量: 827.028
• InChiKey: NMYYUYKSXZEBAL-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  [1,2:5,6-η-(1,5-cycloodiene)]triphenylphosphinechlororuthenium 、 sodium tris(2-mercapto-1-methylimidazolyl)borate 、 三甲基膦 以 四氢呋喃 、 二氯甲烷 为溶剂， 以75%的产率得到[Rh(PMe3)(PPh3)(B(methimazolyl)3)]Cl
  参考文献：
  名称：

  Metallaboratranes:  Tris(methimazolyl)borane Complexes of Rhodium(I)

  摘要：

  The syntheses and reactivity of the first rhodaboratranes, [RhX(PPh3){B(mt)(3)}] (X = Cl, H) and [Rh(eta(4)-C8H12){B(mt)(3)}]Cl, are described in detail together with preliminary investigations of the mechanistic processes involved. The subsequent exploitation and circumvention of the lability of [RhCl(PPh3){B(mt)(3)}] in the synthesis of a range of isonitrile, [Rh(CNR)(PPh3){B(mt)(3)}]Cl (R = Bu-t, C6H3Me2-2,6, C6H2Me3-2,4,6), phosphine, [Rh(PMe3)(n)(PPh3)(2-n){B(mt)(3)}]Cl (n = 0, 1, 2), and dialkyldithiocarbamate, [Rh(S-2-NEt2){B(mt)(3)}]Cl, complexes is described, along with the attempted synthesis of [Rh(CN'Bu)(2){B(mt)(3)}]Cl from [Rh(eta(4)-C8H12){B(mt)(3)}]Cl. Single-crystal X-ray structure determinations of [Rh(L)(L'){B(mt)(3)}]Cl (L = (CNBu)-Bu-t, CN(C6H3Me2-2,6), L' = PPh3; L = L' = PMe3) are reported.

  DOI：

  10.1021/om050772+