7-O-(4-methoxybenzyl)-4,5-di-O-benzyl-3,6-anhydro-L-ido-hept-1-enitol | 524722-59-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 7-O-(4-methoxybenzyl)-4,5-di-O-benzyl-3,6-anhydro-L-ido-hept-1-enitol
• CAS: 524722-59-6
• 化学式: C₂₉H₃₂O₅
• 分子量: 460.57
• InChiKey: XKBVVTONKZFFGS-QUAHOIDUSA-N

反应信息

• 作为反应物：
  描述：

  7-O-(4-methoxybenzyl)-4,5-di-O-benzyl-3,6-anhydro-L-ido-hept-1-enitol 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 二氯甲烷 、 水 为溶剂， 以87%的产率得到4,5-di-O-benzyl-3,6-anhydro-L-ido-hept-1-enitol
  参考文献：
  名称：

  Cycloheptanic sugar mimetics, bridging the gap in the homologous series of carbocyclic analogues

  摘要：

  The cycloheptanic analogues Of alpha-D-glucopyranose and P-D-mannopyranose have been synthesized. These two members of a new class of carbocyclic sugar mimetics are filling the gap between already existing cyclohexanic and cyclooctanic classes of sugar mimetics. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)01402-3
• 作为产物：
  描述：

  Trifluoro-methanesulfonic acid (1R,2S,3R,4S)-2,3,4-tris-benzyloxy-1-(4-methoxy-benzyloxymethyl)-hex-5-enyl ester 以 二氯甲烷 为溶剂， 以1.08 g的产率得到7-O-(4-methoxybenzyl)-4,5-di-O-benzyl-3,6-anhydro-L-ido-hept-1-enitol
  参考文献：
  名称：

  Cycloheptanic sugar mimetics, bridging the gap in the homologous series of carbocyclic analogues

  摘要：

  The cycloheptanic analogues Of alpha-D-glucopyranose and P-D-mannopyranose have been synthesized. These two members of a new class of carbocyclic sugar mimetics are filling the gap between already existing cyclohexanic and cyclooctanic classes of sugar mimetics. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(02)01402-3