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(2E,2'E)-((1R,2R)-1-((2R,3S)-3-(cinnamoyloxy)-3,6-dihydro-2H-pyran-2-yl)-2-phenylethane-1,2-diyl) bis(3-phenylacrylate) | 1262487-71-7

中文名称
——
中文别名
——
英文名称
(2E,2'E)-((1R,2R)-1-((2R,3S)-3-(cinnamoyloxy)-3,6-dihydro-2H-pyran-2-yl)-2-phenylethane-1,2-diyl) bis(3-phenylacrylate)
英文别名
——
(2E,2'E)-((1R,2R)-1-((2R,3S)-3-(cinnamoyloxy)-3,6-dihydro-2H-pyran-2-yl)-2-phenylethane-1,2-diyl) bis(3-phenylacrylate)化学式
CAS
1262487-71-7
化学式
C40H34O7
mdl
——
分子量
626.706
InChiKey
HVEWEMPKQOALOD-KRCGYVBQSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    7.19
  • 重原子数:
    47.0
  • 可旋转键数:
    12.0
  • 环数:
    5.0
  • sp3杂化的碳原子比例:
    0.12
  • 拓扑面积:
    88.13
  • 氢给体数:
    0.0
  • 氢受体数:
    7.0

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量
  • 下游产品
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为反应物:
    描述:
    (2E,2'E)-((1R,2R)-1-((2R,3S)-3-(cinnamoyloxy)-3,6-dihydro-2H-pyran-2-yl)-2-phenylethane-1,2-diyl) bis(3-phenylacrylate) 在 pyridinium dichromate 、 sodium acetate 作用下, 以 二氯甲烷 为溶剂, 反应 12.0h, 以85%的产率得到(+)-tricinnamate
    参考文献:
    名称:
    Stereoselective total synthesis of styryl-lactones: (+)-crassalactones B and C, (+)-howiionol A, (+)-tricinnamate, (+)-goniofufurone and (+)-dicinnamoyl goniofufurone
    摘要:
    The total synthesis of (+)-crassalactone B (+)-crassalactone C (+)-howiionol A (+)-tricinnamate (+)-goniofufurone and (+)-dicinnamoyl goniofufurone is achieved by a chit-on approach starting from diacetone D-glucose (DAG) Mitsunobu inversion Wittig olefination and ring closing metatheses were used as key steps for (+)-howiionol A and (+)-tricinnamate Meldrum s acid was used for the synthesis of (+)-crassalactone C (+)-goniofufurone and (+)-dicinnamoyl goniofufurone Yamaguchi esterification was used for (+)-crassalactone B while a Grignard reaction followed by concomitant deallylation was first reported in the synthesis of (+)-dicinnamoyl goniofufurone (C) 2010 Elsevier Ltd All rights reserved
    DOI:
    10.1016/j.tetasy.2010.10.016
  • 作为产物:
    描述:
    (1R,2R)-2-hydroxy-2-((2R,3S)-3-hydroxy-3,6-dihydro-2H-pyran-2-yl)-1-phenylethyl cinnamate肉桂酸4-二甲氨基吡啶N,N'-二环己基碳二亚胺 作用下, 以 二氯甲烷 为溶剂, 反应 12.0h, 以73%的产率得到(2E,2'E)-((1R,2R)-1-((2R,3S)-3-(cinnamoyloxy)-3,6-dihydro-2H-pyran-2-yl)-2-phenylethane-1,2-diyl) bis(3-phenylacrylate)
    参考文献:
    名称:
    Stereoselective total synthesis of styryl-lactones: (+)-crassalactones B and C, (+)-howiionol A, (+)-tricinnamate, (+)-goniofufurone and (+)-dicinnamoyl goniofufurone
    摘要:
    The total synthesis of (+)-crassalactone B (+)-crassalactone C (+)-howiionol A (+)-tricinnamate (+)-goniofufurone and (+)-dicinnamoyl goniofufurone is achieved by a chit-on approach starting from diacetone D-glucose (DAG) Mitsunobu inversion Wittig olefination and ring closing metatheses were used as key steps for (+)-howiionol A and (+)-tricinnamate Meldrum s acid was used for the synthesis of (+)-crassalactone C (+)-goniofufurone and (+)-dicinnamoyl goniofufurone Yamaguchi esterification was used for (+)-crassalactone B while a Grignard reaction followed by concomitant deallylation was first reported in the synthesis of (+)-dicinnamoyl goniofufurone (C) 2010 Elsevier Ltd All rights reserved
    DOI:
    10.1016/j.tetasy.2010.10.016
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