| 1186530-79-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1186530-79-9
• 化学式: C₃₂H₄₃NO₇Si
• 分子量: 581.781
• InChiKey: CDQRTBZCSCNGNT-BEZMCUIASA-N

反应信息

• 作为产物：
  描述：

  、 2,2-二甲氧基丙烷 在 4-甲基苯磺酸吡啶 作用下， 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Total synthesis of the proposed structures of hyacinthacines C2, C3, and their C5-epimers

  摘要：

  Synthesis and structural confirmation of highly oxygenated pyrrolizicline alkaloids, hyacinthacines C-2 [(1S,2R,3R,5R,7S,7aR)-3,5-hydroxymethyl-1,2,7-trihydroxypyrrolizidine], C-3[1S,2R,3R,5S,7R,7aR)-3,5-hydroxymethyl-1,2,7-trihydroxypyrrolizidine], and their C5-epimers were achieved on the basis of the highly divergent method employing (S)-(-)-2-pyrrolidone-5-carboxylic acid as the starting material. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.06.072