| 148386-96-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 148386-96-3
• 化学式: C₆H₁₄Cl₂O₅W
• 分子量: 420.93
• InChiKey: AYUDMDWWCZAWMW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氧代氯化钨 、 二乙二醇二甲醚 以 not given 为溶剂， 以54%的产率得到
  参考文献：
  名称：

  Diglyme (C₆H₁₄O₃) complexes of molybdenum and tungsten: crystal structures of [MO₂Cl₂(C₆H₁₄O₃)](M = Mo or W)

  摘要：

  The diglyme complexes [MO2Cl2(C6H14O3)] (M = Mo or W) have been prepared by reaction of MoO2Cl2 or WOCl4-Me3SiOSiMe3 with diglyme. X-Ray diffraction studies have shown that in these complexes the metals exhibit distorted-octahedral geometry, with cis-dioxo and trans-chloro ligands. Two ether oxygen atoms are co-ordinated trans to the oxo ligands leaving one terminal oxygen atom of the ligand uncomplexed. Assignments of metal-ligand stretching vibrations as observed by IR and Raman spectroscopy are presented. Variable temperature C-13-{H-1} NMR spectra in CD2Cl2 solution indicate rapid intramolecular exchange between free and bound terminal oxygen atoms.

  DOI：

  10.1039/dt9930001045