[Zn(1,10-phenanthroline)(C6H5NHC(S)NP(O)(O-iPr)2)2] | 1041860-36-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Zn(1,10-phenanthroline)(C6H5NHC(S)NP(O)(O-iPr)2)2]
• CAS: 1041860-36-9
• 化学式: C₃₈H₄₈N₆O₆P₂S₂Zn
• 分子量: 876.305
• InChiKey: JDFFHECTDYHRFQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 bis[N-(diisopropoxyphosphoryl)-N'-phenylthiocarbamido-O,S]zinc(II) 以 苯 为溶剂， 以82%的产率得到[Zn(1,10-phenanthroline)(C6H5NHC(S)NP(O)(O-iPr)2)2]
  参考文献：
  名称：

  Studies on zinc(II) complexes with N-thioacylamidophosphates: X-ray crystal structure of the [Zn(RC(S)NP(O)(OiPr)2)2] (R = NH2, tBuNH, c-C6H11NH)

  摘要：

  The photoluminescent properties of 17 zinc(II) chelates [Zn(RC(S)NP(C)(OiPr)(2)-0,S)(2)] (R = Ph (1a), PhNH (1b), p-BrPh (1c), p-MeCC6H4NH (1d), p-BrC6H4NH (le), NH2 (1f), iPrNH (1g), tBuNH (1h), Et2N (1i), c-C5H10N (1j), c-OC4HgN (1k), c-C6H11NH (1I), aminobenzo-15-crown-5 (1m)) and [Zn(B) (RC(S)NP(O)(OiPr)(2)-O,S)(2)](R=Ph, B=2,2'-bipyridine (2a); R=Ph, B=1,10-phenanthroline (2b); R = PhNH, B = 2,2'-bipyridine (2c); R = PhNH, B = 1,10-phenanthroline (2d)), are reported. Colorless and air/moisture stable chelate complexes of divalent zinc show blue emission in the solid state when excited with UV light. Complexes If, 1h, 1I were investigated by single crystal X-ray diffraction. The zinc(II) atom in complexes If, 1h, 1I is in a distorted tetrahedral O2S2 environment formed by the C=S sulphur atoms and the P=O oxygen atoms of two deprotonated ligands. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.005