| 1015789-72-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1015789-72-6
• 化学式: C₁₂H₁₀F₄O₂
• 分子量: 262.204
• InChiKey: RIXGCJNBCSOKMY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 邻苯二胺 以 苯 为溶剂， 反应 0.05h， 以230 mg的产率得到1,4-dihydro-2,3-diethyl-1,4,11,12-tetrafluoro-1,4-ethenophenazine
  参考文献：
  名称：

  o-Fluoranil Chemistry: Diels–Alder versus Hetero-Diels–Alder Cycloaddition

  摘要：

  The title quinone undergoes [4 + 2] cycloadditions in two ways, Diels-Alder on the ring and hetero-Diels-Alder by attack at the oxygens. The latter mode of reaction is strongly favored thermodynamically, but there is a kinetic bias favoring the normal Diels-Alder addition that often prevails, especially with cycloaddends that are not electron-rich.

  DOI：

  10.1021/jo7026678
• 作为产物：
  描述：

  3-己炔 、 五氟苯酚 在 硝酸 作用下， 以 二氯甲烷 、 苯 为溶剂， 反应 31.0h， 生成
  参考文献：
  名称：

  o-Fluoranil Chemistry: Diels–Alder versus Hetero-Diels–Alder Cycloaddition

  摘要：

  The title quinone undergoes [4 + 2] cycloadditions in two ways, Diels-Alder on the ring and hetero-Diels-Alder by attack at the oxygens. The latter mode of reaction is strongly favored thermodynamically, but there is a kinetic bias favoring the normal Diels-Alder addition that often prevails, especially with cycloaddends that are not electron-rich.

  DOI：

  10.1021/jo7026678