(-)-(5S,6R,8S,9S,10R,12R,14R)-6,12-diacetoxycass-Δ¹³⁽¹⁵⁾-en-12,16-olide | 1131006-37-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子
• 英文名称: (-)-(5S,6R,8S,9S,10R,12R,14R)-6,12-diacetoxycass-Δ¹³⁽¹⁵⁾-en-12,16-olide
• CAS: 1131006-37-5
• 化学式: C₂₄H₃₄O₆
• 分子量: 418.53
• InChiKey: OVCZSVAAAAZWJU-XHUWMZNQSA-N

反应信息

• 作为产物：
  描述：

  (-)-(5S,6R,8S,9S,10R,12R,14R)-6-acetoxy-12-hydroxycass-Δ¹³⁽¹⁵⁾-en-12,16-olide 、 乙酸酐 在 吡啶 作用下， 以1.0 mg的产率得到(-)-(5S,6R,8S,9S,10R,12R,14R)-6,12-diacetoxycass-Δ¹³⁽¹⁵⁾-en-12,16-olide
  参考文献：
  名称：

  Cassane Diterpenes from Caesalpinia bonduc

  摘要：

  Three cassane diterpene hemiketals, caesalpinolide-C, caesalpinolide-D, caesalpinolide-E and one cassane furanoditerpene were isolated from Caesalpinia bonduc. The molecular structures were elucidated using NMR spectroscopy in combination with IR, UV and mass spectral data and relative stereochemistries were determined through ROESY correlation. The isolated compounds were tested for their antiproliferative activity against MCF-7 (breast adenocarcinoma), DU145 (prostate carcinoma), C33A (Cervical carcinoma) and Vero (African green monkey kidney fibroblast) cells. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.phytochem.2008.12.008