bis(4,4'-diethyl-3,3',5,5'-tetramethyldipyrroylmethenate)copper(II) | 15415-91-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: bis(4,4'-diethyl-3,3',5,5'-tetramethyldipyrroylmethenate)copper(II)
• 英文别名: Cu(4,4'-diethyl-3,3',5,5'-tetramethyl-2,2'-dipyrrolylmethene(-1H))2；Cu(3,3',5,5'-tetramethyl-4,4'-diethyldipyrrolylmethene-2,2'(-1H))2；copper;(2Z)-4-ethyl-2-[(4-ethyl-3,5-dimethylpyrrol-1-id-2-yl)methylidene]-3,5-dimethylpyrrole
• CAS: 15415-91-5
• 化学式: C₃₄H₄₆CuN₄
• 分子量: 574.312
• InChiKey: QCGZXEOHXQQKGE-KNGYMQEQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(4,4'-diethyl-3,3',5,5'-tetramethyldipyrroylmethenate)copper(II) 以 solid 为溶剂， 生成 氮 、 copper(II) oxide
  参考文献：
  名称：

  Thermal properties of ligands, salts and metal complexes of linear oligopyrroles

  摘要：

  The effect of structure on the thermal properties of dipyrrolylmethanes, dipyrrolylmethenes, bis (dipyrrolylmethenes), their salts, and chelates is analyzed proceeding from the results of thermogravimetric analysis. The common tendency is a decrease in the thermal stability of compounds with a disturbed symmetry of alkyl substitution of ligands and with a higher degree of their alkylation, with the increased size of alkyl substituents, with the nitrogen atom in the five-member cycles replaced by S or O. The opposite effect occurs at the change in the mode of attaching methylene spacer in going from 2,2'- to 3,3'-bis(dipyrrolylmethenes). The effects of the themostabilization of the ligands of linear oligopyrroles in the composition of chelates and HBr salts are evaluated quantitatively.

  DOI：

  10.1134/s1070363209090163
• 作为产物：
  描述：

  2,4,8,10-tetramethyl-3,9-diethyldipyrrolyl-5,7-methene 、 copper diacetate 以 N,N-二甲基甲酰胺 为溶剂， 生成 bis(4,4'-diethyl-3,3',5,5'-tetramethyldipyrroylmethenate)copper(II)
  参考文献：
  名称：

  Trends in formation and stability of homo- and heteroligand d-metal complexes with 2,2′-dipyrrolylmethenes in dimethylformamide

  摘要：

  The reactions of symmetric and nonsymmetric alkyl-substituted 2,2'-dipyrrolylmethenes with Cu(II), Ni(II), Co(II), Zn(II), Cd(II), and Hg(II) acetates in dimethylformamide solutions at 298.15 K were studied. The formation of hetero- and homoligand complexes was observed in the systems studied depending on the concentration conditions and the nature of the complexing metal. The stepped and complete constants of formation for metal complexes were determined. The key trends of the influence of the metal and ligand nature on the stabilization of the complexes were established.

  DOI：

  10.1134/s0036023609110084

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 127, page 1724 - 1727
  作者：

  DOI：——

  日期：——
• Fischer, H.; Halbig, P.; Walach, B., Liebigs Annalen der Chemie, 1927, vol. 452, p. 268 - 302
  作者：Fischer, H.、Halbig, P.、Walach, B.

  DOI：——

  日期：——