1-(pyren-1-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole | 1424621-77-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1-(pyren-1-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole
• 英文别名: 1-(pyren-3-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole；1-Pyren-1-yl-2,5-dithiophen-2-ylpyrrole
• CAS: 1424621-77-1
• 化学式: C₂₈H₁₇NS₂
• 分子量: 431.582
• InChiKey: HLJCPBUSZJBGRJ-UHFFFAOYSA-N

物化性质

• 沸点：
  653.2±45.0 °C(Predicted)
• 密度：
  1.33±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  31
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  芘 在 palladium 10% on activated carbon 、 乙酸酐 、 copper(II) nitrate 、 对甲苯磺酸 、 一水合肼 作用下， 以 四氢呋喃 、 乙醇 、 乙酸乙酯 、 甲苯 为溶剂， 生成 1-(pyren-1-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole
  参考文献：
  名称：

  A new processable and fluorescent polydithienylpyrrole electrochrome with pyrene appendages

  摘要：

  A new hybrid compound, namely 1-(pyren-3-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole (SNS-P), was polymerized via both chemical and electrochemical methods. Chemically obtained soluble polydithienylpyrrole (c-PSNS-P) bearing pyrene appendages is a homogeneous and uniform polymer with a number averaged molecular weight of 15,200 g/mol. The polymer exhibits both multi-electrochromic and fluorescent properties. Upon oxidation, the color of electrochemically obtained polymer (e-PSNS-P) changes from yellowish orange to greenish yellow and to green/blue and finally to blue. In addition, the polymer induces yellowish orange (564 nm) and bright orange emission (613 nm) in solution and solid states, respectively. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2012.12.023

文献信息

• Electrochemical synthesis, characterization and capacitive properties of novel thiophene based conjugated polymer
  作者：Burcu Çelik、İlhami Çelik、Hacer Dolaş、Hakan Görçay、Yücel Şahin、A. Sezai Saraç、Kadir Pekmez

  DOI：10.1016/j.reactfunctpolym.2014.07.014

  日期：2014.10

  In this paper, a novel thiophene based monomer, 1-(pyren-1-yl)-2,5-di(thiophen-2-yl)-1H-pyrrole, PThP, was synthesized and characterized by 1H NMR and 13C NMR spectroscopic methods. The electrochemical behavior and electropolymerization of this novel monomer were performed on pencil graphite electrode (PGE) by cyclic voltammetry. The effect of solvent, dopant, scan number and scan rate on the electropolymerization

  本文合成了一种新型的噻吩基单体1-（pyren-1-yl）-2,5-di（thiophen-2-yl）-1H-吡咯PThP，并通过1 H NMR和13表征13 C NMR光谱法。通过循环伏安法在铅笔石墨电极（PGE）上进行了这种新型单体的电化学行为和电聚合。研究了溶剂，掺杂剂，扫描次数和扫描速率对共轭聚合物薄膜电聚合和性能的影响。聚（PThP）薄膜的电容特性通过电化学阻抗谱（EIS）进行了测试。计算出在0.1 M高氯酸四丁铵/二氯甲烷溶液中以25 mV / s扫描速率进行的30个循环中获得的共轭聚合物改性PGE的最高比电容值，为25.45 mF cm - 2。共轭聚合物修饰电极的表面形态通过扫描电子显微镜（SEM）确定。