[Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(C4TMS)2(C6H5NCHNC6H4C2HN3CH2C6H5)] | 853774-91-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: [Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(C4TMS)2(C6H5NCHNC6H4C2HN3CH2C6H5)]
• CAS: 853774-91-1
• 化学式: C₈₁H₈₁N₁₁O₆Ru₂Si₂
• 分子量: 1562.92
• InChiKey: FXFQGIZHKODUQO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(C6H5NCHNC6H4C2HN3CH2C6H5)Cl] 、 (4-trimethylsilyl-1,3-butadiynyl)lithium 以 四氢呋喃 为溶剂， 以52%的产率得到[Ru2(N,N'-di(m-methoxyphenyl)formamidinato)3(C4TMS)(C6H5NCHNC6H4C2HN3CH2C6H5)]
  参考文献：
  名称：

  Covalent Modification of Diruthenium Alkynyl Compounds:  Novel Application of Click Reactions in Organometallic Chemistry

  摘要：

  Diruthenium alkynyl compounds containing one or two 1,2,3-triazoles were prepared via the Cu(I)-catalyzed 1,3-dipolar cycloaddition reaction (click reaction). Electrochemical, magnetic, and molecular structural features of the click products indicate that peripheral modification with the 1,2,3-triazole substituent induces minimal changes in both the molecular structure and electronic properties of Ru-2 alkynyl compounds.

  DOI：

  10.1021/om0501632