(2-(N-methyl)imidazolylmethyl)(2-pyridylmethyl)(2-quinolylmethyl)amine | 758695-92-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: (2-(N-methyl)imidazolylmethyl)(2-pyridylmethyl)(2-quinolylmethyl)amine
• CAS: 758695-92-0
• 化学式: C₂₁H₂₁N₅
• 分子量: 343.431
• InChiKey: IXFFSNCPQWMCCT-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  manganese (II) nitrate tetrahydrate 、 (2-(N-methyl)imidazolylmethyl)(2-pyridylmethyl)(2-quinolylmethyl)amine 以 甲醇 为溶剂， 以42%的产率得到[Mn((2-(N-methyl)imidazolylmethyl)(2-pyridylmethyl)(2-quinolylmethyl)amine)(η1-NO3)(η2-NO3)]
  参考文献：
  名称：

  Five manganese(II) complexes with seven- or eight-coordinated Mn(II), revealing different coordination modes for the nitrato ligands

  摘要：

  Four seven-coordinated manganese(II) complexes [Mn(tpa)(eta(1)-NO3)(eta(2)-NO3)] (1), [Mn(bpia)(eta(1)-NO3)(eta(2)-NO3)] (2), [Mn(tpa)(eta(1)-NO3)(eta(2)-NO3)] (3), [Mn(tpa)(eta(1)-NO3)(eta(2)-NO3)] (4), and one octacoordinated manganese(II) complex [Mn(bppza)(mu(2)-NO3)(2)] (5) have been synthesized and characterized using the tripodal tetradentate ligands tpa, bpia, bipa, ipqa, and bppza (tpa: tris(2-pyridylmethyl)amine, bpia: bis(2-pyridylmethyl)(2-(N-methyl)imidazolylmethyl)amine, bipa: bis-(2-(N-methyl)imidazolylmethyl)(2-pyridylmethyl)amine, ipqa: (2-(N-methyl)imidazolylmethyl)(2-pyridylmethyl)(2-quinolylmethyl)amine, and bppza: bis(2-pyridylmethyl)(2-pyrazylmethyl)amine). The crystal structures for all compounds have been determined. 1, 2 and 3 crystallize in the triclinic space group P (1) over bar, 4 crystallizes in the orthorhombic space group Pbca, whereas the eight-coordinated 5 crystallizes in the monoclinic space group P2(1)/n. All compounds have one bidentate bound nitrate group in common. The coordination number and its geometry depend on the coordination mode of the second nitrate group. The coordination polyhedron for 1, 2, 3 and 4 is best described as an oblate octahedron and the one for 5 as a doubly oblate octahedron. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.03.021