1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine | 1201393-98-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine
• 英文别名: PNNP；Ph2PN(Ph)N(Ph)PPh2；1,2-Bis(diphenylphosphanyl)-1,2-diphenylhydrazine
• CAS: 1201393-98-7
• 化学式: C₃₆H₃₀N₂P₂
• 分子量: 552.595
• InChiKey: LAQQRPHEKAZMPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  40
• 可旋转键数：
  9
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine 以 CH₂Cl₂ 为溶剂， 以97%的产率得到cis-[PtCl2(Ph2PN(Ph)N(Ph)PPh2-P,P)]
  参考文献：
  名称：

  Synthesis, Coordination Chemistry, and Catalysis of the First 1,2-Bis(diphenylphosphino)-1,2-diphenylhydrazine, Ph₂PN(Ph)N(Ph)PPh₂

  摘要：

  The reaction of chlorodiphenylphosphine with dilithiophydrazobeneze gave 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine, [PPh2N(Ph)N(Ph)PPb2] (1). Treatment of 1 with NiCl2(DME), PdCl2(PhCN)(2), and PtCl2(COD) resulted in the formation of complexes of the type cis-[MCl2-{Ph2PN(Ph)N(Ph)PPh2}] (M = Ni (3), Pd (4), Pt (5)). The molecular Structures of the starting ligand I and the complexes 3, 4, and 5 have been determined by X-ray diffraction, The ligand 1 and its Ni(II) complex 3 were evaluated for their catalytic activity in the oligo-/polymerization of ethylene using methylaluminoxane (MAO) and triethylaluminium (TEA) as cocatalyst.

  DOI：

  10.1021/om900925b
• 作为产物：
  描述：

  diphenylphosphino-1,2-diphenylhydrazine 、 二苯基氯化膦 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以43%的产率得到1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine
  参考文献：
  名称：

  Synthesis, Coordination Chemistry, and Catalysis of the First 1,2-Bis(diphenylphosphino)-1,2-diphenylhydrazine, Ph₂PN(Ph)N(Ph)PPh₂

  摘要：

  The reaction of chlorodiphenylphosphine with dilithiophydrazobeneze gave 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine, [PPh2N(Ph)N(Ph)PPb2] (1). Treatment of 1 with NiCl2(DME), PdCl2(PhCN)(2), and PtCl2(COD) resulted in the formation of complexes of the type cis-[MCl2-{Ph2PN(Ph)N(Ph)PPh2}] (M = Ni (3), Pd (4), Pt (5)). The molecular Structures of the starting ligand I and the complexes 3, 4, and 5 have been determined by X-ray diffraction, The ligand 1 and its Ni(II) complex 3 were evaluated for their catalytic activity in the oligo-/polymerization of ethylene using methylaluminoxane (MAO) and triethylaluminium (TEA) as cocatalyst.

  DOI：

  10.1021/om900925b
• 作为试剂：
  描述：

  乙烯 在 四氢呋喃 、 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine 、 三乙胺 作用下， 以 甲苯 为溶剂， 45.0 ℃ 、3.0 MPa 条件下， 反应 1.5h， 生成 丁烯 、 1-己烯 、 辛烯 、 正癸烯
  参考文献：
  名称：

  Synthesis, Coordination Chemistry, and Catalysis of the First 1,2-Bis(diphenylphosphino)-1,2-diphenylhydrazine, Ph₂PN(Ph)N(Ph)PPh₂

  摘要：

  The reaction of chlorodiphenylphosphine with dilithiophydrazobeneze gave 1,2-bis(diphenylphosphino)-1,2-diphenylhydrazine, [PPh2N(Ph)N(Ph)PPb2] (1). Treatment of 1 with NiCl2(DME), PdCl2(PhCN)(2), and PtCl2(COD) resulted in the formation of complexes of the type cis-[MCl2-{Ph2PN(Ph)N(Ph)PPh2}] (M = Ni (3), Pd (4), Pt (5)). The molecular Structures of the starting ligand I and the complexes 3, 4, and 5 have been determined by X-ray diffraction, The ligand 1 and its Ni(II) complex 3 were evaluated for their catalytic activity in the oligo-/polymerization of ethylene using methylaluminoxane (MAO) and triethylaluminium (TEA) as cocatalyst.

  DOI：

  10.1021/om900925b