[In(μ-OCMe2(CF3))(OCMe2(CF3))]2 | 245499-50-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [In(μ-OCMe2(CF3))(OCMe2(CF3))]2
• 英文别名: tris[(1,1,1-trifluoro-2-methylpropan-2-yl)oxy]indigane
• CAS: 245499-50-7
• 化学式: C₂₄H₃₆F₁₈In₂O₆
• 分子量: 992.157
• InChiKey: QYSOJGZRKIUDKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-三氟甲基-2-丙醇 、 以 正己烷 为溶剂， 以68%的产率得到[In(μ-OCMe2(CF3))(OCMe2(CF3))]2
  参考文献：
  名称：

  Indium Fluoroalkoxide Compounds

  摘要：

  Reactions of indium amide complexes with fluorinated alcohols give indium fluoroalkoxide complexes. In[N-t-Bu(SiMe3)](3) reacts with 3 equiv of (CF3)Me2COH to give the homoleptic alkoxide dimer [In{mu-OCMe2(CF3)}-{OCMe2(CF3)}(2)](2), but reactions involving the more acidic alcohols (CF3)(2)MeCOH and (CF3)(2)CHOH yield products containing t-BuNH2, which is derived from the amide ligands. Thus, In[N-t-Bu(SiMe3)](3) reacts with (CF3)(2) MeCOH to give In[OCMe(CF3)(2)](3)(H2N-t-Bu) and with (CF3)(2)CHOH to yield In[OCH(CF3)(2)](3)(H2N-t-Bu)(3) and [H3N-t-Bu] [In(OCH(CF3)(2))(4)(H2N-t-Bu)]. Reactions of (CF3)(2)MeCOH and (CF3)(2)CHOH with In(tmp)(3) (tmp = the anion derived from 2,2,6,6-tetramethylpiperidine) and In(NEt2)(3) are less complicated. In(tmp)(3) reacts with 3 equiv of (CF3)(2)CHOH to give In[OCH(CF3)(2)](3)(Htmp) and with 4 equiv of (CF3)(2)CHOH or (CF3)(2)MeCOH to yield the salt compounds [H(2)tmp][In{OCR(CF3)(2)}(4)] (R = H, Me). Trigofial bipyramidal [H2NEt2][In(OCH(CF3)(2))(4)(HNEt2)] and octahedral mer-In[OCMe(CF3)(2)](3)(py)(3) are isolated from reactions involving In(NEt2)(3). Crystal structure determinations of [In{mu-OCMe2(CF3)}{OCMe2(CF3)(2)}(4)], In[OCMe(CF3)(2)}(4)(H2N-t-Bu] [In(OCH(CF3)(2)}(4)(H2N-t-Bu)]. EtOEt, In[OCH(CF3)(2)](3)(Htmp), [H(2)tmp] [In{OCMe(CF3)(2)}(4)], In[OCMe(CF3)(2)](3)(py)(3), and [H2NEt2][In{OCH(CF3)(2)}(4)(HNEt2)] were carried out.

  DOI：

  10.1021/ic990315j